Amine-Based Compound for OLED Efficiency and Lifespan

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Solution Overview

Problem

Current light-emitting devices face limitations in achieving optimal performance in terms of driving voltage, efficiency, and lifespan due to challenges in hole transportability and chemical reactivity, particularly in the use of amine-based compounds in organic light-emitting devices.

Innovation Solution

Incorporating an amine-based compound represented by a specific formula within the interlayer and capping layers of the light-emitting device, which enhances hole transportability and reduces chemical reactivity, thereby improving the device's efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If amine-based compounds are used in light-emitting devices to improve hole transportability, then device efficiency is improved, but chemical reactivity increases leading to reduced lifespan

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure of amine-based compounds by introducing specific substituents and functional groups (such as carbazole, triphen胺, and their derivatives) to adjust the balance between hole transportability and chemical stability. This structural parameter change allows the compound to maintain high hole transport efficiency while reducing excessive chemical reactivity that would otherwise degrade the device lifespan.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite amine-based compounds that combine multiple functional moieties (e.g., electron-donating amine groups with electron-withdrawing substituents) within a single molecular structure. This composite approach enables the material to simultaneously achieve good hole transport properties through the amine group while the incorporated substituents provide enhanced chemical stability and reduced reactivity, thus resolving the contradiction between efficiency and lifespan.

Inventive Principle:
Principle #40Composite materials

2Stress or pressure

If amine-based compounds with high hole transportability are used, then driving voltage is reduced, but chemical reactivity increases causing shorter device lifespan

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice lifespan
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The patent adjusts molecular parameters of amine-based compounds by varying substituent types, positions, and configurations to optimize the relationship between electrical conductivity (affecting driving voltage) and chemical stability. By carefully selecting substituents such as fluorine, chlorine, or bulky aromatic groups, the compound achieves low driving voltage through enhanced hole transport while the same structural modifications simultaneously reduce chemical reactivity and improve device lifespan.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the energy levels of amine-based compounds are fine-tuned to improve efficiency, then device performance is enhanced, but the complexity of compound design and synthesis increases

Engineering Contradiction:
Improvedevice efficiencyVSAvoidcompound design complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent adopts a segmented molecular design approach where the amine-based compound is divided into distinct functional modules: a core amine structure for hole transport, and separate substituent units for energy level adjustment. This segmentation allows researchers to independently optimize each module's function and then combine them, systematically tuning energy levels to achieve high device efficiency while managing design complexity through modular assembly rather than holistic redesign.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention utilizes systematic parameter changes in substituent groups (such as varying chain lengths, aromatic ring substitutions, or electron-withdrawing/donating groups) to fine-tune energy levels in a predictable manner. By establishing structure-property relationships, the patent enables efficient optimization of device efficiency through controlled parameter adjustments without requiring complex de novo design, thus enhancing performance while keeping the design process manageable.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20240224795A1Light-emitting device including amine-based compound, electronic apparatus including the light-emitting device, light-emitting equipment, and the amine-based compound
Publication Date: 2024.07.04 SAMSUNG DISPLAY CO LTD
  • US20240224795A1 patent drawing
  • US20240224795A1 patent drawing
  • US20240224795A1 patent drawing

AI summary

An amine-based compound represented by Formula 1, a light-emitting device including the amine-based compound, and an electronic apparatus and an electronic equipment, each including the light-emitting device are provided. The light-emitting device includes a first electrode, a second electrode on the first electrode, and an interlayer between the first electrode and the second electrode and including the amine-based compound.