Amine Oxide Polymer Composite Absorbent for Organic Solvent Removal

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Solution Overview

Problem

Conventional absorbents are ineffective in efficiently removing water-soluble organic contaminants and solvents from water sources, requiring costly and time-consuming methods like distillation, and existing technologies struggle to address the widespread contamination of groundwater by organic materials.

Innovation Solution

A composite absorbent compound comprising 30-55% amine oxide and 30-55% polymer, optionally with a preservative, which is applied to a substrate and dried to form a thin film or gel, capable of absorbing water-soluble solvents and contaminants from water or air without the need for distillation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional absorbents are used to remove organic contaminants from water, then some absorption occurs, but the absorption efficiency is insufficient and distillation is required

Engineering Contradiction:
Improveabsorption efficiencyVSAvoidremoval completeness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent combines amine oxide and polymer in a composite absorbent material. The amine oxide component provides affinity for polar functional groups of organic contaminants, while the polymer matrix provides structural support and swelling capacity. This composite structure achieves both high absorption efficiency and complete removal of water-soluble organics without requiring distillation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the absorbent by controlling the ratio of amine oxide to polymer (30:70 to 70:30), adjusting cross-linking density, and optimizing particle size. These parameter changes enable the absorbent to effectively capture both polar and non-polar organic contaminants with high efficiency and completeness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If distillation is used to remove water-soluble solvents from water, then complete removal is achieved, but the process is time-consuming and costly

Engineering Contradiction:
Improveremoval completenessVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent replaces the thermal distillation process with a chemical absorption mechanism. The amine oxide-polymer composite selectively binds water-soluble organic solvents through chemical affinity and physical absorption, achieving complete removal without the time-consuming and energy-intensive heating and phase separation required by distillation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The composite absorbent acts as an intermediary substance that mediates the separation between water and organic solvents. The amine oxide groups form intermediate complexes with polar organic molecules, facilitating their removal from water through absorption rather than requiring direct thermal separation through distillation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If conventional absorbents are used, then application is simple, but the absorption rate and retention quantity are insufficient

Engineering Contradiction:
Improveease of applicationVSAvoidabsorption rate
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent utilizes the porous structure of the polymer matrix to provide high surface area for absorption. The cross-linked polymer network creates interconnected pores that facilitate rapid diffusion of organic contaminants into the absorbent interior, significantly increasing the absorption rate while maintaining simple application procedures.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The absorbent is pre-treated during manufacturing to optimize its absorption characteristics. The amine oxide and polymer are pre-combined in specific ratios and pre-cross-linked to create an optimized absorption structure, so that when applied, the absorbent immediately achieves high absorption rate and retention quantity without requiring additional preparation steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The absorbent compound significantly enhances the removal of organic contaminants and solvents from water, including those with hydrophilic and hydrophobic properties, in a single-step process, improving existing water treatment systems' efficiency and reducing costs.

Implementation Method 1

The adsorption and absorption of organics has been a problem for over a century

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Absorbents are used to recover liquids by retaining liquid and/or gases distributed throughout its molecular structure

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

which may result in the solid absorbent to swell

Methodology Applied
Scientific EffectSwelling:

Implementation Method 4

Alcohol is soluble in water, as the hydroxyl group in the alcohol forms hydrogen bonds with water molecules

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 5

Organic compounds dissolve into water because the affinity of their polar functional groups for water is stronger than the repulsion of their non-polar groups from water

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Implementation Method 6

the affinity of their polar functional groups for water is stronger than the repulsion of their non-polar groups from water

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentUS20240109052A1Absorbent and method of making and use of the same
Publication Date: 2024.04.04 THOR JASON
  • US20240109052A1 patent drawing
  • US20240109052A1 patent drawing
  • US20240109052A1 patent drawing

AI summary

An absorbent compound and method of making the same, where the absorbent compound includes an amine oxide that comprises about 30% to about 55% of the absorbent compound and a polymer that comprises about 30% and about 55% of the absorbent compound.