Amine Oxide Surfactant in Water-Soluble Unit Dose Articles

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Solution Overview

Problem

Water-soluble unit dose articles with liquid detergent compositions face issues of premature rupture leading to spillage and contamination, and increasing viscosity with rheology modifiers compromises cleaning performance by reducing active ingredient levels.

Innovation Solution

Incorporating amine oxide as an amphoteric surfactant in the liquid detergent composition within a water-soluble unit dose article, which is packaged with a recloseable container and water-soluble film, reduces liquid leakage from ruptured units while maintaining effective cleaning performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the viscosity of the liquid detergent composition is increased to reduce leakage from ruptured unit dose articles, then liquid leakage is reduced, but cleaning performance deteriorates due to lower levels of cleaning actives

Engineering Contradiction:
Improveliquid leakage reductionVSAvoidcleaning performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the chemical composition parameters of the detergent by incorporating amine oxide surfactants, which alter the surface tension and rheological properties of the liquid detergent. This allows the detergent to maintain lower viscosity (preserving cleaning active levels) while achieving adequate compression resistance to prevent premature rupture and leakage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite detergent formulation combining multiple surfactant types including amine oxide compounds. This composite approach allows the detergent to achieve both low viscosity for cleaning performance and sufficient compression resistance through the synergistic effects of different surfactant molecules working together.

Inventive Principle:
Principle #40Composite materials

2Reliability

If rheology modifiers are added to increase viscosity and reduce leakage, then liquid leakage is reduced, but cleaning performance deteriorates due to reduced cleaning active levels

Engineering Contradiction:
Improveliquid leakage reductionVSAvoidcleaning performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent extracts and eliminates the need for separate rheology modifiers from the detergent formulation. Instead of adding dedicated viscosity-control additives that would displace cleaning actives, the invention uses amine oxide surfactants that inherently provide both cleaning functionality and adequate compression resistance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The amine oxide surfactants serve multiple functions simultaneously: they act as cleaning agents, provide compression resistance to prevent premature rupture, and eliminate the need for separate rheology modifiers. This multi-functionality resolves the contradiction by replacing a single-function additive with a multi-functional ingredient.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of amine oxide in the detergent composition minimizes liquid leakage from prematurely ruptured unit dose articles while providing excellent grease cleaning benefits and maintaining cleaning performance.

Implementation Method 1

the liquid laundry detergent composition comprises a non-soap anionic surfactant and an amphoteric surfactant, wherein the amphoteric surfactant is amine oxide

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP3279303B2Water-soluble unit dose article comprising an amphoteric surfactant
Publication Date: 2022.03.23 PROCTER & GAMBLE CO
  • EP3279303B2 patent drawingFigure 1
  • EP3279303B2 patent drawing
  • EP3279303B2 patent drawing

AI summary

The present invention relates to water-soluble unit dose articles comprising an amphoteric surfactant, methods of making and methods of use.