Amine-Based Pyrene Compound for Blue OLED Color Purity

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face challenges in achieving high color purity and efficiency for blue light emission, particularly in meeting standards like NTSC or sRGB, due to limitations in the materials used for the emitting layers.

Innovation Solution

The development of an amine-based compound represented by Formula 1, which includes a core structure of substituted pyrene, chrysene, or diphenyl-benzofluoranthene, is used in the organic light-emitting diode. This compound is integrated into the emission layer, allowing for efficient blue light emission with improved color purity by optimizing the substituents and their binding sites, thereby enhancing the OLED's electric and color characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional materials are used in the emitting layer, then the OLED structure is simple and manufacturing is easier, but color purity and efficiency for blue light emission are insufficient

Engineering Contradiction:
Improvecolor purity of blue light emissionVSAvoidcomplexity of emitting layer material
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical structure parameters of the emitting layer materials by introducing specific amine-based compounds with defined molecular weights and functional groups. This structural parameter change enables the material to emit blue light with higher color purity while maintaining manufacturing feasibility through conventional OLED fabrication processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining amine-based compounds with specific core structures (pyrene, chrysene, or diphenyl-benzofluoranthene) and substituent groups. This composite approach achieves superior blue light emission characteristics that cannot be obtained with single conventional materials, resolving the contradiction between performance improvement and material complexity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional emitting layer materials are used, then manufacturing processes remain simple, but efficiency and driving voltage characteristics are inadequate

Engineering Contradiction:
Improvecurrent density and emission efficiencyVSAvoidease of manufacturing OLED
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes electrical parameters by selecting amine-based compounds with specific molecular weights (50-500 g/mol) and functional group configurations. These parameter changes enhance charge transport properties and emission efficiency while maintaining compatibility with existing OLED manufacturing processes, thus improving productivity without significantly increasing manufacturing difficulty.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If standard emitting layer compounds are used, then the device structure remains simple, but the ability to meet color standards (NTSC or sRGB) is insufficient

Engineering Contradiction:
Improvecolor accuracy according to standardsVSAvoidcomplexity of compound structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies local quality principle by introducing specific substituent groups at particular positions on the core molecular structure. This localized structural modification targets the optical properties of the emitting layer, enabling precise control over emission wavelength and color purity to meet NTSC or sRGB standards without requiring complete redesign of the entire OLED structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent achieves precise color control by adjusting chemical structure parameters of the amine-based compounds, including molecular weight, functional group types, and substituent positions. These parameter changes enable the emitting layer to produce blue light with specific color coordinates that meet international display standards, resolving the contradiction between color accuracy and structural simplicity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine-based compound enables OLEDs to emit blue light with high color purity, meeting the NTSC or sRGB standards, and provides good electric characteristics such as low driving voltage and high current density, while reducing manufacturing complexity and costs.

Implementation Method 1

Holes injected from the anode move to the emitting layer through the hole transport layer, and electrons injected from the cathode move to the emitting layer through the electron transport layer. The holes and electrons are recombined with each other in the emitting layer to generate excitons. Then, the excitons transition from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10665788B2Amine-based compound, organic light-emitting diode including the same, and organic light-emitting apparatus including the amine-based compound
Publication Date: 2020.05.26 SAMSUNG DISPLAY CO LTD
  • US10665788B2 patent drawing
  • US10665788B2 patent drawing
  • US10665788B2 patent drawing

AI summary

Embodiments of the present invention include an amine-based compound represented by Formula 1, an organic light-emitting diode including the amine-based compound, and an organic light-emitting apparatus including the amine-based compound.