Amine Transport Layer Compounds for OLED Efficiency and Lifespan

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Solution Overview

Problem

Existing light-emitting devices face challenges in achieving high emission efficiency and long lifespan, necessitating the development of materials that can stabilize these characteristics.

Innovation Solution

Incorporating amine compounds, specifically those represented by Formulas 1-1 to 1-3, into functional layers such as the hole transport region and electron transport region of light-emitting devices, which include structures like hole injection, transport, and blocking layers, to enhance efficiency and longevity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in light emitting devices, then the device can be manufactured with standard materials, but the emission efficiency and lifespan are insufficient

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial selection complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical structure parameters of hole transport materials by introducing specific substituent groups (fluorine atoms, deuterium atoms, carbazole groups, dibenzofuran groups) at defined positions of the core molecular structure. These parameter changes in molecular composition and structure optimize the material's electronic properties, leading to improved emission efficiency and device lifespan while maintaining manufacturability through established synthesis routes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining multiple functional groups (amine, carbazole, dibenzofuran, fluorine substituents) within a single molecular framework. This creates a composite functional structure that integrates hole transport capability, thermal stability, and enhanced emission efficiency, resolving the contradiction between performance improvement and material complexity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional hole transport materials are used, then the device structure remains simple, but emission efficiency is insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies local quality modification by strategically placing specific functional groups (fluorine atoms at positions 2 and 6, carbazole groups at positions 3 and 7, dibenzofuran groups at positions 5 and 9) at defined locations on the molecular core. This localized functionalization optimizes electron distribution and hole transport pathways at critical positions, enhancing emission efficiency without requiring complete structural redesign.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the molecular structure into distinct functional modules: a central molecular core, amine groups for hole transport, carbazole groups for thermal stability, dibenzofuran groups for structural rigidity, and fluorine substituents for efficiency enhancement. This segmentation allows each module to contribute its specific function, achieving high emission efficiency through coordinated action of specialized segments rather than a monolithic complex structure.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of amine compounds in these layers results in light-emitting devices with improved emission efficiency and extended lifespan, meeting the desired performance criteria.

Implementation Method 1

a hole transport region disposed between the first electrode and the emission layer, and an electron transport region disposed between the emission layer and the second electrode

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

holes and electrons injected from a first electrode and a second electrode recombine in an emission layer so that a light emitting material in an emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12503459B2Light emitting device and amine compound for the same
Publication Date: 2025.12.23 SAMSUNG DISPLAY CO LTD
  • US12503459B2 patent drawing
  • US12503459B2 patent drawing
  • US12503459B2 patent drawing

AI summary

A light emitting device, includes: a first electrode; a second electrode disposed on the first electrode; and at least one functional layer disposed between the first electrode and the second electrode and including an amine compound of Formula 1:in Formula 1, the variables are described herein.