Amino-Containing Vinylsilane Polymer Modifier

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Solution Overview

Problem

There is a need for a polymer modifier that can effectively enhance polymer properties, as existing methods for introducing functional groups into polymers have limitations in achieving a balance of desired properties such as melt tension, fluidity, rigidity, impact resistance, and tensile properties.

Innovation Solution

Amino-containing vinylsilane compounds with specific structures are used as modifiers, prepared through reactions involving vinylsilane compounds, amine compounds, and platinum catalysts, which improve polymer properties by modifying their chemical structure and physical characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If polymers are modified using conventional functional group introduction methods (maleic anhydride, N-vinylalkylamide, acrylamide), then specific polymer properties are improved, but the ability to achieve a balanced improvement across multiple properties (melt tension, fluidity, rigidity, impact resistance) is limited

Engineering Contradiction:
Improvepolymer property improvement capabilityVSAvoidmodification method complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The amino-containing vinyl silane compound serves as a universal modifier that can simultaneously improve multiple polymer properties including melt tension, fluidity, rigidity, and impact resistance. This single compound replaces the need for multiple different modifiers that would otherwise be required to achieve similar balanced property improvements, making the modification approach both simpler and more versatile

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention introduces a specific chemical structure parameter - the amino-containing vinyl silane compound with the formula (1) - that enables balanced property improvement. By changing the modifier type to this specific compound class with its unique structural parameters (amino group, silane group, vinyl group combination), the patent achieves simultaneous improvement across multiple polymer properties that conventional modifiers cannot achieve alone

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If amino-containing vinyl silane compounds are used as polymer modifiers, then multiple polymer properties are significantly improved, but the complexity of the modification method increases due to the specific synthesis requirements

Engineering Contradiction:
Improvepolymer property improvement capabilityVSAvoidmodifier synthesis ease
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The amino-containing vinyl silane compound is synthesized and prepared in advance through a dedicated synthesis process involving vinyl silane compound, amine compound, and platinum catalyst. This preliminary preparation of the specialized modifier allows it to be readily available for polymer modification applications, enabling the significant multi-property improvements without requiring complex modification procedures during actual polymer processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The amino-containing vinyl silane compound acts as an intermediary substance that bridges the gap between conventional modifiers and the desired balanced property improvements. Its specific molecular structure - containing amino, silane, and vinyl groups - allows it to interact with polymer chains in unique ways that simultaneously achieve multiple property enhancements, serving as a mediating agent that translates chemical structure into balanced physical property improvements

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amino-containing vinylsilane compounds significantly enhance polymer properties, allowing for improved melt tension, fluidity, rigidity, and impact resistance, making them suitable for various applications.

Implementation Method 1

reacting a vinylsilane compound of formula (4) with an amine compound of formula (5) in the presence of a platinum catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP2287170B1Amino-containing vinylsilane compounds and method of making the same
Publication Date: 2014.04.02 SHIN ETSU CHEMICAL CO LTD
  • EP2287170B1 patent drawingFigure 1
  • EP2287170B1 patent drawingFigure 2
  • EP2287170B1 patent drawingFigure 3

AI summary

Vinylsilane compounds having a specific amino group, typically diethylaminopropyldimethylvinylsilane, N-methylpiperazinylpropyldimethylvinylsilane, and bistrimethylsilylaminopropyldimethylvinylsilane are novel and useful as a modifier for polymers.