Ammonia Calculation in Gas Samples via Hydrogen Analyzer

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Solution Overview

Problem

Current methods for analyzing ammonia in gas samples during heat treatment processes, such as gas nitriding, are costly and prone to errors due to the interference of hydrogen and other gases, leading to unreliable hydrogen concentration readings.

Innovation Solution

A method and system utilizing a hydrogen analyzer to measure output signals from both a first gas sample containing ammonia and a second gas sample with ammonia eliminated, allowing for calculation of ammonia concentration using a hydrogen error correction value, thereby reducing costs and improving accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If expensive ammonia analyzers are used to analyze ammonia concentration, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improveammonia concentration measurement precisionVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent uses a hydrogen analyzer as an intermediary device to indirectly measure ammonia concentration. Instead of using a dedicated expensive ammonia analyzer, the system employs a hydrogen analyzer with a catalyst that converts ammonia to hydrogen, allowing the hydrogen analyzer to detect ammonia levels through the generated hydrogen signal. This intermediary approach resolves the contradiction by achieving ammonia measurement precision through a different measurement pathway that avoids the need for complex and expensive dedicated ammonia analysis equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical/chemical measurement system of dedicated ammonia analyzers with a catalytic conversion system followed by hydrogen detection. The catalyst chamber converts ammonia chemically to hydrogen, and the hydrogen analyzer detects the resulting hydrogen concentration. This substitution uses a different physical principle (hydrogen detection via thermal conductivity or other methods) to achieve ammonia measurement, thereby reducing device complexity and cost while maintaining measurement precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Device complexity

If hydrogen analyzers are used to analyze hydrogen concentration, then device complexity is reduced, but measurement precision deteriorates due to ammonia interference

Engineering Contradiction:
Improvedevice complexityVSAvoidhydrogen concentration measurement precision
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The patent extracts ammonia from the gas sample stream by passing it through a catalyst chamber where ammonia is selectively converted to hydrogen. This separation step removes the interfering ammonia from the original mixture, allowing the hydrogen analyzer to then measure hydrogen concentration without interference. The extraction principle resolves the contradiction by physically separating the interfering substance before measurement, thereby maintaining measurement precision while using a simpler hydrogen analyzer device.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs preliminary catalytic conversion of ammonia to hydrogen before the hydrogen analysis step. By pre-converting ammonia in the catalyst chamber, the system eliminates the interference problem before the actual hydrogen measurement occurs. This preliminary action ensures that when the hydrogen analyzer measures the gas sample, the ammonia has already been transformed, thus maintaining measurement precision without requiring a complex ammonia-specific analyzer.

Inventive Principle:
Principle #10Preliminary action

3Measurement precision

If frequent water burette readings are taken to monitor heat treatment process, then measurement precision is improved, but productivity decreases

Engineering Contradiction:
Improveammonia concentration measurement precisionVSAvoidprocess monitoring efficiency
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces the manual water burette measurement system with an automated catalytic conversion and hydrogen detection system. The catalyst chamber continuously converts ammonia to hydrogen, and the hydrogen analyzer automatically detects and quantifies the ammonia concentration in real-time. This substitution eliminates the need for frequent manual readings, thereby maintaining measurement precision while dramatically improving productivity and process monitoring efficiency through continuous automated measurement.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent implements continuous monitoring by maintaining a continuous flow of gas through the catalyst chamber and hydrogen analyzer. Unlike discrete manual water burette readings, the automated system provides continuous real-time data on ammonia concentration throughout the heat treatment process. This continuous useful action resolves the contradiction by enabling both high measurement precision and high productivity, as the system continuously monitors without requiring manual intervention or slowing down the production process.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides a cost-effective and accurate method for calculating ammonia levels in gas samples, minimizing human intervention and suitable for both industrial and lab environments, while reducing errors caused by hydrogen and other gases.

Implementation Method 1

when hydrogen analyzers are used to analyze the concentration of hydrogen in the gas sample, the ammonia in a balance of nitrogen changes the thermal conductivity of the gas sample, thereby creating error in the hydrogen analyzer

Methodology Applied
Scientific EffectThermal conductivity detection: Conduction (thermal)

Data Source

PatentUS10816524B2Method for calculating amount of ammonia in gas sample
Publication Date: 2020.10.27 CATERPILLAR INC
  • US10816524B2 patent drawing
  • US10816524B2 patent drawing
  • US10816524B2 patent drawing

AI summary

A method for calculating an amount of ammonia present in a gas sample is provided. The method includes receiving a first gas sample by a hydrogen analyzer. The first gas sample contains ammonia. The method also includes receiving a second gas sample by the hydrogen analyzer. The second gas sample is formed by eliminating ammonia from the gas sample. The method further includes measuring, by the hydrogen analyzer, an output signal for each of the first and second gas samples. The method includes calculating the amount of ammonia present in the gas sample based on the measured output signal for each of the first and second gas samples and a hydrogen error correction value.