Ammonia Combustion Catalyst Lowers Light-Off Temperature

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Solution Overview

Problem

Ammonia combustion engines face challenges with slow flame propagation and low cycle efficiency due to high minimum ignition energy, which limits their performance and efficiency.

Innovation Solution

Incorporating an ammonia combustion catalyst, such as metal oxides like Ag2O, MnO2, or CuO, in the combustion chamber to lower the light-off temperature and increase combustion speed, potentially reducing the need for additional fuel components like hydrogen.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If ammonia is used as fuel in internal combustion engine, then carbon-free energy carrier is achieved with high energy density, but flame propagation speed is slow and ignition energy requirement is high

Engineering Contradiction:
Improveenergy densityVSAvoidflame propagation speed
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

A catalyst is introduced as an intermediary substance in the combustion chamber to facilitate the combustion of ammonia. The catalyst lowers the activation energy barrier, enabling faster flame propagation and reduced ignition energy requirements while maintaining ammonia's carbon-free energy carrier properties

Inventive Principle:
Principle #24Intermediary (Mediator)

2Use of energy by moving object

If ammonia is used as fuel in internal combustion engine, then carbon-free energy carrier is achieved, but combustion duration is long which reduces cycle efficiency

Engineering Contradiction:
Improvecarbon-free energy carrierVSAvoidcombustion duration
Core Design Contradiction:
Use of energy by moving objectVSDuration of action of moving object

Solution Approach 1:

The catalyst acts as a mediator that accelerates the combustion reaction rate of ammonia, thereby reducing the overall combustion duration. This enables the engine to complete more combustion cycles per unit time, improving cycle efficiency while maintaining the carbon-free advantage of ammonia fuel

Inventive Principle:
Principle #24Intermediary (Mediator)

3Use of energy by moving object

If ammonia is used as fuel in internal combustion engine, then renewable carbon-free energy is achieved, but high minimum ignition energy limits performance

Engineering Contradiction:
Improverenewable carbon-free energyVSAvoidignition energy requirement
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The catalyst serves as a mediator that reduces the minimum ignition energy required for ammonia combustion. By providing an alternative reaction pathway with lower activation energy, the catalyst enables easier ignition while preserving ammonia's renewable and carbon-free energy characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst enhances combustion efficiency by reducing the light-off temperature and increasing the effective combustion speed, thereby improving the performance of ammonia-combusting engines.

Implementation Method 1

Incorporating an ammonia combustion catalyst, such as metal oxides like Ag2O, MnO2, or CuO, in the combustion chamber to lower the light-off temperature and increase combustion speed

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4230853A1Ammonia-burning combustion engine
Publication Date: 2023.08.23 JOHNSON MATTHEY PLC

AI summary

The present invention relates to an ammonia-burning combustion engine. In particular, the present invention relates to an internal combustion engine for the combustion of ammonia, the engine comprising one or more combustions chambers comprising an ammonia combustion catalyst. The invention further relates to a method for operating an internal combustion engine by the combustion of ammonia, the method comprising contacting ammonia with a heated ammonia combustion catalyst in a combustion chamber of the engine to combust the ammonia.