Ammonia Scrubbing Matrix Slime Control via Flocculation

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Solution Overview

Problem

Current methods for purifying air containing ammonia using scrubbing treatments are costly due to frequent matrix maintenance and high energy requirements for air passage, despite the use of nitrification treatments that slow slime formation and enhance ammonia removal.

Innovation Solution

The method involves adding a flocculating agent to the collected aqueous liquid, subjecting it to a clearance step, and using the resulting liquid for scrubbing treatment, while performing nitrification under acidic conditions and utilizing encapsulated microorganisms and specific flocculating agents like ferric salts to minimize slime formation and substrate availability for nitrifying bacteria.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If nitrification treatment is performed to slow slime formation, then matrix maintenance frequency is reduced, but the cost of operation increases due to the need for continuous liquid treatment and replacement

Engineering Contradiction:
Improvematrix service lifeVSAvoidoperational cost
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameters of the aqueous liquid by adding flocculating agents (aluminium salts, ferric salts) and controlling pH levels to optimize nitrification. This transforms the liquid from a simple washing medium to a chemically optimized solution that enhances ammonia removal efficiency and reduces slime formation, thereby extending matrix service life while managing operational costs through improved process efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces flocculating agents as intermediary substances that facilitate the separation and removal of slime and organic matter from the aqueous liquid. These intermediaries (aluminium salts, ferric salts, polymers) mediate between the nitrification process and the final liquid output, enabling effective slime removal while maintaining the liquid's ability to continue scrubbing ammonia from air

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If the total amount of washing liquid is kept limited, then investment cost and discharge cost are reduced, but the effectiveness of ammonia collection may be compromised

Engineering Contradiction:
Improvewashing liquid volumeVSAvoidammonia collection efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent implements a continuous circulation system where the aqueous liquid is repeatedly used for scrubbing ammonia from air. The liquid undergoes continuous nitrification treatment and slime removal, maintaining its effectiveness over time. This continuous reuse maximizes the utilization of each unit of liquid, reducing the total volume needed while maintaining high ammonia collection efficiency through sustained contact between the liquid and ammonia-containing air

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent optimizes the chemical parameters of the limited aqueous liquid through controlled nitrification and addition of flocculating agents. By adjusting pH, nutrient composition, and adding coagulants, the system maximizes the liquid's capacity to remove ammonia from air, thereby achieving high productivity with reduced quantity of washing liquid

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If flocculating agent is added to prevent slime formation, then matrix cleaning frequency is reduced, but the complexity of liquid treatment process increases

Engineering Contradiction:
Improvematrix service lifeVSAvoidliquid treatment process complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs self-service mechanisms where the flocculating agents (aluminium salts, ferric salts, polymers) automatically precipitate and remove slime from the aqueous liquid through natural settling processes. The system uses the liquid's own flow dynamics and gravity to separate sludge from the clarified liquid, eliminating the need for complex mechanical filtration or external treatment systems while maintaining effective slime removal

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent modifies the chemical parameters of the aqueous liquid by adding flocculating agents and controlling pH levels to optimize nitrification. This transforms the liquid from a simple washing medium to a chemically optimized solution that enhances ammonia removal efficiency and reduces slime formation, thereby extending matrix service life while managing operational costs through improved process efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the total washing liquid volume, minimizes slime formation, and maintains effective ammonia removal, leading to lower operational costs and extended matrix lifespan with reduced energy consumption.

Implementation Method 1

a flocculating agent is added to at least part of the collected aqueous liquid; the liquid obtained following the addition of the flocculating agent is subjected to a clearance step

Methodology Applied
Scientific EffectFlocculation: Flocculation

Implementation Method 2

at least part of the collected aqueous liquid is subjected to a nitrification treatment, and at least part of the liquid subjected to the nitrification treatment is used as the reprocessed aqueous liquid

Methodology Applied
Scientific EffectNitrification: Oxidation

Implementation Method 3

the nitrification treatment is performed by use of encapsulated microorganisms

Methodology Applied
Scientific EffectBiological oxidation: Aerobic Digestion

Implementation Method 4

a matrix is understood to be a surface-enlarging structure that has a large number of passageways for allowing the passage of air to be purified, and also allows for water applied onto the structure to flow over the structure slowly and with an increased surface area

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 5

water applied onto the structure to flow over the structure slowly and with an increased surface area, as a result of which a prolonged contact time between the water and air passed through is achieved

Methodology Applied
Scientific EffectSurface adhesion: Adhesive

Implementation Method 6

the nitrification treatment is performed under such conditions that the pH of the reprocessed aqueous liquid is lowered to less than 7

Methodology Applied
Scientific EffectAcid-base chemistry: Chemical Bonding

Data Source

PatentEP2308583B1Scrubbing ammonia from air
Publication Date: 2013.12.11 INNO
  • EP2308583B1 patent drawing

AI summary

The invention relates to a method for subjecting air that contains ammonia and needs to be purified to a scrubbing treatment, wherein the air to be purified is passed through a matrix, an aqueous liquid is introduced onto the matrix at a relatively high position and flows over the matrix, the aqueous liquid is collected at a relatively low position and is subjected to a reprocessing treatment to yield a reprocessed aqueous liquid that is used again for carrying out a scrubbing treatment of air. The method according to the invention is characterized in that at least part of the collected aqueous liquid is subjected to a nitrification treatment, and at least part of the liquid subjected to the nitrification treatment is used as the reprocessed aqueous liquid for carrying out again the scrubbing treatment of air that contains ammonia and needs to be purified.