Ammonia Slip Detection via Modulated DEF Injection

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Solution Overview

Problem

Existing SCR systems face challenges in accurately distinguishing between nitrogen oxides (NOx) and ammonia (NH3) in exhaust gases due to common sensors' inability to differentiate between the two, leading to incorrect DEF injection adjustments and potential NH3 slip.

Innovation Solution

The system employs an electronic control unit that modulates the DEF injection frequency and uses a band-pass filter to analyze sensor signals, determining the presence of NOx or NH3 based on signal variations at the modulation frequency, allowing precise adjustment of DEF supply to prevent NH3 slip.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a common NOx sensor is used to detect ammonia in exhaust gas, then the sensor responds to both NOx and NH3 approximately equally, but the electronic control cannot distinguish between sensor signals due to NOx and NH3

Engineering Contradiction:
Improveammonia detection accuracyVSAvoidsignal differentiation capability
Core Design Contradiction:
Measurement precisionVSLoss of information

Solution Approach 1:

The system modulates the DEF injection in a periodic manner at a specific frequency, causing corresponding periodic variations in ammonia production. By analyzing sensor signals at this modulation frequency using spectral analysis or band-pass filtering, the system can distinguish ammonia-related signal components from other sources, enabling accurate ammonia slip detection despite sensor cross-sensitivity to NOx

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The system changes the injection frequency parameter of DEF delivery and analyzes sensor signals at this specific frequency. By tuning the analysis to match the modulation frequency, the system extracts ammonia-related information from the composite sensor signal, resolving the inability to distinguish between NOx and NH3 responses

Inventive Principle:
Principle #35Parameter changes

2Reliability

If DEF is over-injected to ensure complete NOx reduction, then NOx conversion is maximized, but ammonia may pass unreacted through the SCR chamber resulting in NH3 slip

Engineering Contradiction:
ImproveNOx reduction effectivenessVSAvoidammonia slip
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The system uses real-time ammonia detection through spectral analysis of sensor signals to provide feedback on actual ammonia slip conditions. Based on this feedback, the ECU dynamically adjusts DEF injection rates to maintain optimal levels - increasing injection when ammonia slip is detected and reducing it when ammonia levels are appropriate, thereby preventing both incomplete NOx reduction and excessive ammonia slip

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts DEF injection rates based on real-time ammonia slip detection. Rather than using fixed injection rates, the system continuously monitors ammonia levels through frequency-based sensor analysis and adapts the injection strategy to maintain optimal operation under varying engine conditions and ammonia slip risks

Inventive Principle:
Principle #15Dynamics

3Measurement precision

If a sensor specifically sensitive only to NH3 is used, then accurate ammonia detection is achieved, but such sensors are more complex and expensive than common NOx sensors

Engineering Contradiction:
Improveammonia detection specificityVSAvoidsensor system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The system uses signal processing techniques as an intermediary between the common sensor and the control system. By applying frequency-based filtering and spectral analysis to the sensor output, the system extracts ammonia-specific information from the composite signal, effectively creating a virtual ammonia-selective sensor using software rather than hardware modifications

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system replaces the need for specialized ammonia-selective sensor hardware with electronic signal processing methods. By using frequency-domain analysis and band-pass filtering on the output from a standard sensor, the system achieves ammonia-specific detection capability without the complexity and cost of specialized sensor hardware

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables accurate differentiation between NOx and NH3, optimizing DEF injection to minimize NH3 slip and ensure effective NOx reduction, thereby improving emission control and system efficiency.

Implementation Method 1

Using a band-pass filter, the electronic control unit analyzes the sensor signal at the known frequency of DEF modulation

Methodology Applied
Scientific EffectBand-pass filtering: Filter (electronic)

Data Source

PatentEP3139014B1System and method for detecting tailpipe ammonia slip
Publication Date: 2018.03.21 DEERE & CO
  • EP3139014B1 patent drawingFigure 1~2
  • EP3139014B1 patent drawingFigure 3
  • EP3139014B1 patent drawingFigure 4

AI summary

System and method of treating exhaust gas from an internal combustion engine using selective catalytic reduction and a modulated supply of diesel exhaust fluid. The modulated supply of diesel exhaust fluid induces variations in nitrogen oxides exiting a selective catalytic reduction chamber. An electronic control unit inputs a signal from a sensor that senses the variations in nitrogen oxides. The signal is filtered at the modulation frequency to isolate peak-to-peak variations in the signal caused by the modulated diesel exhaust fluid supply. Based on whether the peak-to-peak variations are above a threshold thus indicating a predominance of nitrogen oxides over reductant, the electronic control unit adjusts the supply of diesel exhaust fluid.