Ammonia Storage Material Segmentation for Exhaust Gas Treatment

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Solution Overview

Problem

Current systems for treating exhaust gases with low concentrations of ammonia, such as those from livestock houses, are inefficient and costly, particularly when dealing with variable and low ammonia concentrations.

Innovation Solution

The system employs an ammonia storage material, such as zeolite, to accumulate and concentrate ammonia, which is then treated with an ammonia oxidation catalyst in the gas phase, allowing for efficient catalytic destruction of ammonia at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If scrubber and biofilter systems are used to treat exhaust gases, then pollutant concentrations are reduced, but investment cost and operational cost increase

Engineering Contradiction:
Improvepollutant concentrationsVSAvoidinvestment cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent extracts and removes ammonia from the exhaust gas stream using a selective catalytic reduction system, separating the ammonia treatment from the rest of the exhaust gas composition. This allows targeted treatment of the harmful component without requiring comprehensive treatment of all pollutants, reducing system complexity and cost.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces a selective catalytic reduction system with specific catalysts and reagents as intermediaries to facilitate ammonia removal. This intermediary system enables efficient ammonia treatment at lower costs compared to conventional scrubber and biofilter systems, while maintaining effectiveness in reducing pollutant concentrations.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If scrubber and biofilter systems are used to treat exhaust gases, then pollutant concentrations are reduced, but volume of water consumed increases

Engineering Contradiction:
Improvepollutant concentrationsVSAvoidvolume of water consumed
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent replaces the water-based scrubber system with a selective catalytic reduction system that uses chemical reactions and catalysts instead of liquid absorption. This substitution eliminates the need for large volumes of water while maintaining effective ammonia removal, directly addressing the water consumption issue.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the operational parameters from water-based absorption processes to catalytic chemical reactions. By transforming the treatment mechanism from physical absorption to chemical catalysis, the system achieves pollutant removal without requiring high volumes of water, thereby reducing water consumption while maintaining treatment effectiveness.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If ammonia storage material is heated to release stored ammonia, then ammonia concentration for catalytic treatment increases, but energy consumption increases

Engineering Contradiction:
Improveammonia concentrationVSAvoidenergy consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent implements periodic heating cycles of the ammonia storage material, alternating between heating phases to release ammonia and cooling phases to allow re-absorption. This periodic action ensures continuous ammonia supply to the catalytic converter while minimizing total energy consumption by heating only the necessary portion of the storage material at any given time.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent segments the ammonia storage material into multiple zones or beds, allowing selective heating of only the portion that requires regeneration. This segmentation enables efficient ammonia release from a small fraction of the total storage capacity while the rest of the storage material continues to absorb ammonia from the exhaust gas, reducing overall energy consumption.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables effective treatment of low-concentration ammonia exhaust gases at low temperatures, reducing energy consumption and production costs while minimizing by-products and maintaining air quality standards.

Implementation Method 1

an ammonia storage material arranged to receive an exhaust gas from the exhaust gas inlet

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a heating device for heating gas before it passes through the selected portion of the ammonia storage material to release ammonia stored therein

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 3

an ammonia oxidation catalyst arranged downstream of a selected portion of the ammonia storage material

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

ammonia oxidation catalyst arranged downstream of a selected portion of the ammonia storage material

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS12325003B2Exhaust gas treatment system
Publication Date: 2025.06.10 JOHNSON MATTHEY PLC
  • US12325003B2 patent drawing

AI summary

The invention relates to an exhaust system for the treatment of an exhaust gas comprising ammonia in an amount of up to 250 ppm, the system comprising: an exhaust gas inlet; an ammonia storage material arranged to receive an exhaust gas from the exhaust gas inlet; an ammonia oxidation catalyst arranged downstream of a selected portion of the ammonia storage material; and a heating device for heating gas before it passes through the selected portion of the ammonia storage material to release ammonia stored therein for treatment on the ammonia oxidation catalyst, wherein the system is configured so that the selected portion of the ammonia storage material changes over time. The invention further relates to a livestock house comprising the exhaust system and a method of treating an ammonia-containing gas.