Ammonia Synthesis Flow Control for Compressor Surge Prevention

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Solution Overview

Problem

Existing ammonia synthesis systems face challenges in coping with flow rate changes during production cycles, leading to non-uniform flow rate distribution, temperature deviations within catalyst beds, surge phenomena in compressors, and increased energy requirements for ammonia separation.

Innovation Solution

An ammonia synthesis system incorporating a compressor, air separation unit, coolers, and catalyst beds with backflow prevention plates and distribution devices, along with flexible cooling modes and microwave heating, to maintain uniform flow distribution, prevent surge phenomena, and optimize energy use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If the flow rate of raw material is decreased, then energy consumption is reduced, but flow rate distribution becomes non-uniform and temperature deviation in catalyst bed increases

Engineering Contradiction:
Improveenergy consumptionVSAvoidflow rate distribution uniformity
Core Design Contradiction:
Loss of energyVSStability of the object's composition

Solution Approach 1:

The catalyst bed is divided into multiple zones with independent flow control. Distribution devices are positioned at different locations within the catalyst bed to separately control flow rates to each zone, ensuring uniform flow distribution even when overall flow rate is decreased.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Flow control valves are installed in each mixed gas supply line to dynamically adjust flow rates to different catalyst beds based on actual production needs. This dynamic adjustment maintains uniform flow distribution while adapting to changing operational conditions and energy consumption requirements.

Inventive Principle:
Principle #15Dynamics

2Productivity

If the flow rate of raw material is changed, then production volume is adjusted, but compressor surge phenomenon occurs

Engineering Contradiction:
Improveammonia production volumeVSAvoidcompressor operation stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A flow rate detection device is installed to monitor the actual flow rate of mixed gas. The control unit receives feedback from this detection device and adjusts the flow control valves accordingly, preventing compressor surge by maintaining optimal flow conditions even when production volume is adjusted.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts flow rates to different catalyst beds based on real-time detection of overall flow rate changes. This dynamic control prevents sudden flow variations that would cause compressor surge while allowing flexible adjustment of ammonia production volume.

Inventive Principle:
Principle #15Dynamics

3Productivity

If multiple catalyst beds are used, then ammonia synthesis yield is improved, but temperature uniformity between central and outer parts deteriorates

Engineering Contradiction:
Improveammonia synthesis yieldVSAvoidtemperature uniformity in catalyst bed
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The catalyst bed is segmented into multiple zones with independent flow control. Distribution devices are positioned at different locations to ensure uniform flow distribution across all zones, which maintains temperature uniformity while supporting high productivity through multiple catalyst beds.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the catalyst bed are provided with customized flow control. Flow control valves are installed in each mixed gas supply line to adjust flow rates to specific catalyst beds, ensuring that temperature and flow conditions are optimized locally in both central and outer parts of the catalyst bed.

Inventive Principle:
Principle #3Local quality

4Productivity

If flow rate is increased to improve production, then ammonia synthesis yield increases, but energy consumption for cooling and separation increases

Engineering Contradiction:
Improveammonia production volumeVSAvoidenergy consumption for cooling and separation
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The system dynamically adjusts flow rates to different catalyst beds based on actual production volume requirements. Flow control valves are adjusted in real-time to match the actual ammonia production, preventing excessive energy consumption for cooling and separation when production volume is lower than maximum capacity.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system changes operational parameters including flow rates, temperatures, and pressures to optimize the balance between production volume and energy consumption. By adjusting these parameters dynamically, the system achieves high productivity while minimizing energy requirements for cooling and ammonia separation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system stabilizes compressor operation, maintains uniform temperature across catalyst beds, reduces energy consumption, and enhances ammonia synthesis yield by adapting to flow rate changes, ensuring efficient ammonia separation and extended catalyst life.

Implementation Method 1

a compressor for compressing mixed gas

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

an ammonia synthesis reactor for synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

a first cooler for cooling syngas including ammonia discharged from the ammonia synthesis reactor

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 5

an air separation unit for separating nitrogen from air

Methodology Applied
Scientific EffectFractional distillation: Distillation

Implementation Method 6

a second cooler for heat-exchanging gaseous nitrogen separated by the air separation unit with the syngas cooled by the first cooler

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 7

microwave heating

Methodology Applied
Scientific EffectMicrowave heating: Microwave Radiation

Data Source

PatentUS20250223182A1Ammonia synthesis system and operation method thereof
Publication Date: 2025.07.10 SK INNOVATION CO LTD
  • US20250223182A1 patent drawing
  • US20250223182A1 patent drawing
  • US20250223182A1 patent drawing

AI summary

An ammonia synthesis system, an operation method thereof, and an ammonia synthesis method are provided. The system includes a compressor for compressing mixed gas; a feed supply line for supplying the mixed gas to the compressor; an ammonia synthesis reactor for synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor; an air separation unit for separating nitrogen from air; a first cooler for cooling syngas including ammonia discharged from the ammonia synthesis reactor; and a second cooler for heat-exchanging gaseous nitrogen separated by the air separation unit with the syngas cooled by the first cooler, wherein gaseous nitrogen heat-exchanged by the second cooler is supplied to the feed supply line.