Ammonium-Functionalized Saccharide Polymers for Mining Contaminant Removal

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Solution Overview

Problem

Current approaches for contaminant removal and fines mitigation in mining operations are less effective and more costly than desired, often having an undesirable environmental profile and high operational expenses.

Innovation Solution

The use of functionalized saccharide polymers, derived from a reaction product of a saccharide polymer and diallyldimethylammonium chloride (DADMAC), which can be applied in froth flotation processes for contaminant separation and as a coating to mitigate dust formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional flocculants (organic or inorganic) are used for contaminant removal, then contaminant separation efficiency is improved, but environmental profile deteriorates and production costs increase

Engineering Contradiction:
Improvecontaminant separation efficiencyVSAvoidenvironmental profile
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical structure and properties of biopolymer flocculants by controlling molecular weight, degree of substitution, and functional group composition to optimize both performance and environmental compatibility. This allows achieving conventional flocculant efficiency while maintaining biodegradability and reducing toxicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite flocculant systems combining multiple biopolymer components with complementary functions - some components provide flocculation while others provide biodegradability and environmental safety. This composite approach achieves superior contaminant removal compared to single-component biopolymers while maintaining eco-friendly profile.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If biopolymer flocculants are used instead of organic or inorganic flocculants, then environmental profile is improved, but productivity and flocculating efficiency deteriorate

Engineering Contradiction:
Improveenvironmental profileVSAvoidflocculating efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent systematically optimizes biopolymer parameters including molecular weight distribution, hydroxyl value, and substitution degree to enhance flocculation kinetics and floc strength. These parameter adjustments enable biopolymer flocculants to match or exceed the efficiency of conventional alternatives while maintaining environmental benefits.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces specific functional groups and intermediate structures in the biopolymer chain that act as mediation points for contaminant binding and floc formation. These intermediary structures facilitate efficient contaminant capture while preserving the biodegradable nature of the polymer backbone.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If engineering approaches (ventilation, water sprays, physical barriers) are used for dust control, then dust suppression is improved, but operational cost and complexity increase

Engineering Contradiction:
Improvedust suppressionVSAvoidoperational complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical dust control systems (ventilation, water sprays, physical barriers) with a chemical coating solution that passively suppresses dust generation. The coating forms a protective layer on particulate materials, preventing aerosolization without requiring mechanical intervention or complex operational protocols.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention employs a cost-effective coating formulation that can be applied economically to control dust. The coating material is designed to be applied in small amounts and provides sustained protection, replacing expensive and complex mechanical dust control infrastructure with a simpler, more economical chemical approach.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Object-affected harmful factors

If conventional dust control coatings containing inorganic chloride salts are applied, then dust suppression is improved, but environmental friendliness deteriorates and corrosion increases

Engineering Contradiction:
Improvedust suppressionVSAvoidcorrosion and environmental harm
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent eliminates harmful inorganic chloride salts from the coating formulation while maintaining effective dust suppression through alternative biopolymer-based mechanisms. The coating achieves dust control through natural adhesive and film-forming properties of modified biopolymers, converting a potentially harmful chemical approach into a beneficial, eco-friendly solution that also prevents corrosion.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The functionalized saccharide polymers enhance the efficiency of contaminant removal and dust control, offering improved environmental sustainability and reduced material costs compared to conventional methods.

Implementation Method 1

Froth treatments utilize a flocculant, also known as a flocculating agent or frothing agent, to promote formation of a froth for sequestering a contaminant from a product stream

Methodology Applied
Scientific EffectFlocculation: Flocculation

Implementation Method 2

Another approach for mitigating the presence of fines involves applying a coating to a particulate material, thereby tempering the ability of the fines to aerosolize into dust particles

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 3

The use of functionalized saccharide polymers, derived from a reaction product of a saccharide polymer and diallyldimethylammonium chloride (DADMAC)

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS12234301B2Ammonium-functionalized saccharide polymers and methods for production and use thereof
Publication Date: 2025.02.25 INTEGRITY BIO CHEMICALS LLC
  • US12234301B2 patent drawing
  • US12234301B2 patent drawing
  • US12234301B2 patent drawing

AI summary

Metal contaminants may be problematic in a number of industries, particularly in the mining industry. Fines production and dust control may be similarly problematic in many industries, including the mining industry. Reaction products formed from a saccharide polymer and diallyldimethylammonium chloride (DADMAC) under room temperature to heating conditions in the presence of a hydroxide base or a radical initiator may be effective for promoting removal of metal contaminants from clay-containing substances, such as through froth flotation. The reaction products may also be effective for mitigating fines production and providing dust control by forming a coating upon a plurality of particulates.