Inorganic Amorphous Film Substrate for Gas Barrier

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Solution Overview

Problem

Conventional substrates for liquid crystal display elements and organic ELs lack sufficient gas barrier properties, particularly in preventing moisture and oxygen ingress, which leads to deterioration of the display performance and requires complex sealing methods that are inefficient and costly.

Innovation Solution

A substrate coated with an inorganic amorphous film having a softening temperature of 100 to 800°C and a glass transition temperature of 50 to 500°C, formed via vapor phase deposition, using materials like chalcogenide compositions, phosphate glasses, and fluorophosphate glasses, which provide high gas barrier properties and weather resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a film substrate is used to enable curved displays and reduce weight, then adaptability and weight are improved, but gas barrier property deteriorates

Engineering Contradiction:
Improvecurved display capabilityVSAvoidgas barrier property
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The invention uses a composite structure consisting of a flexible polymer film substrate combined with an inorganic gas barrier layer. The polymer substrate provides flexibility and light weight, while the inorganic layer (such as aluminum oxide, silicon oxide, or multilayer inorganic compounds) provides the necessary gas barrier property. This composite approach allows the substrate to be bent into curves while maintaining effective moisture and oxygen blocking capabilities.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a multilayer film with inorganic compound films and resin films is used to improve gas barrier property, then gas barrier property is improved, but device complexity increases

Engineering Contradiction:
Improvegas barrier propertyVSAvoidfilm structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The gas barrier function is segmented into multiple thin inorganic layers deposited on the polymer substrate. Each inorganic layer can be formed by separate deposition processes, allowing defects in one layer to be compensated by subsequent layers. The segmentation of the barrier function into discrete inorganic layers provides superior gas barrier performance compared to single-layer or resin-based barriers.

Inventive Principle:
Principle #1Segmentation

3Reliability

If conventional sealing methods are used to prevent moisture ingress, then gas barrier property is improved, but productivity deteriorates

Engineering Contradiction:
Improvegas barrier propertyVSAvoidsealing process efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The gas barrier layer is merged with the substrate structure itself rather than being applied as a separate sealing component. The inorganic gas barrier layer is deposited directly onto the polymer substrate in the same manufacturing line, integrating the barrier function into the substrate fabrication process. This eliminates the need for separate sealing operations and significantly improves productivity while maintaining excellent gas barrier properties.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If a single inorganic compound film is used to improve gas barrier property, then gas barrier property is improved, but manufacturing precision deteriorates due to defect propagation

Engineering Contradiction:
Improvegas barrier propertyVSAvoiddefect density control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Multiple inorganic layers are deposited sequentially on the substrate, with each layer acting as a cushion against defects in previous layers. Pinholes, cracks, or other defects in earlier layers are covered and compensated by subsequent layers, ensuring that the overall gas barrier performance is not significantly degraded by individual layer defects. This layered approach provides redundancy and improves manufacturing robustness.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The substrate achieves high transmittance in the visible light region, excellent gas barrier performance, and improved productivity, making it suitable for use in liquid crystal display devices and organic ELs, while maintaining transparency and weather resistance.

Implementation Method 1

an inorganic amorphous film provided on at least one surface of the substrate and having a softening temperature of from 100 to 800° C.

Methodology Applied
Scientific EffectVapor phase deposition: Physical Vapour Deposition

Data Source

PatentUS7923115B2Substrate with film and glass for formation film
Publication Date: 2011.04.12 AGC INC
  • US7923115B2 patent drawing
  • US7923115B2 patent drawing
  • US7923115B2 patent drawing

AI summary

A substrate with film and a glass for forming such a film are provided, wherein the film has high gas barrier property, high transmittance in visible light region, and high productivity since the film provides effective gas barrier property even if the film is a single layer.A substrate with film having an inorganic amorphous film having a softening temperature of from 100 to 800° C. formed on at least one surface of a substrate; or a substrate with film having an inorganic amorphous film having a glass transition temperature of from 50 to 500° C. formed on at least one surface of a substrate. Further, a glass for forming film composed of a borate glass containing B2O3 as the main component, a phosphate glass containing P2O5, a tellurite type composition containing TeO2 as the main component, a bismuth oxide type composition containing Bi2O3 as the main component or a chalcogenide type composition containing at least one type of element selected from the group consisting of S, Se and Te.