Amorphous Layer Etching for Shallow Trench Isolation Air Gaps

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing method for forming a large air gap in shallow trench isolation (STI) structures faces challenges due to high etching tolerance of sacrificial layers, making it difficult to achieve effective isolation in miniaturized integrated circuits.

Innovation Solution

The method involves forming an amorphous layer on the sidewalls of isolation trenches, burying a sacrificial layer within these trenches, and then removing the sacrificial layer to create an air gap, optimizing the etching process by controlling the thickness of the amorphous layer and etching conditions to enhance the etching rate and form a large air gap efficiently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a sacrificial layer is used to form an air gap in STI structure, then the air gap can be formed, but the etching rate is too slow due to high etching tolerance of the sacrificial layer

Engineering Contradiction:
Improveetching rateVSAvoidetching tolerance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of the sacrificial layer by forming an amorphous silicon layer on its surface. This modifies the etching characteristics, enabling the sacrificial layer to be removed at an appropriate rate while maintaining structural integrity during formation. The amorphous silicon layer has different etching properties compared to the crystalline sacrificial layer material, resolving the contradiction between etching rate and etching tolerance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The amorphous silicon layer acts as an intermediary between the sacrificial layer material and the etching process. It serves as a mediator that controls the etching rate, allowing the sacrificial layer to be removed at a manageable speed. This intermediary layer enables precise control over the air gap formation process while maintaining the sacrificial layer's structural stability during earlier processing steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Volume of moving object

If the sacrificial layer thickness is increased to form a large air gap, then the air gap size increases, but the etching time becomes excessively long

Engineering Contradiction:
Improveair gap volumeVSAvoidetching time
Core Design Contradiction:
Volume of moving objectVSLoss of time

Solution Approach 1:

By changing the etching parameters through the introduction of the amorphous silicon layer, the patent enables faster removal of the sacrificial layer. This parameter change allows large air gaps to be formed in reduced time, as the modified sacrificial layer etches at an optimized rate that balances gap size achievement with process efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The amorphous silicon layer is formed on the sacrificial layer surface before the etching process begins. This preliminary action modifies the surface properties to facilitate faster and more controlled etching, enabling the subsequent removal process to complete efficiently regardless of the sacrificial layer thickness required for the desired air gap size.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If conventional etching methods are used on the sacrificial layer, then the process is simple, but the etching rate is insufficient to form large air gaps efficiently

Engineering Contradiction:
Improveprocess simplicityVSAvoidair gap formation speed
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent applies a preliminary step of forming an amorphous silicon layer on the sacrificial layer surface before etching. This additional preliminary action, while adding a step to the process, enables dramatically improved etching rates that justify the added complexity. The modified process achieves large air gap formation in reduced time, balancing the trade-off between process simplicity and manufacturing productivity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the etching rate of the sacrificial layer, allowing for the formation of a large air gap in a shorter time, effectively addressing the challenge of high etching tolerance and improving isolation in semiconductor devices.

Implementation Method 1

forming an amorphous layer on a sidewall surface of the isolation trench. The method further includes forming a sacrificial layer in the isolation trench via the amorphous layer, and forming an air gap layer on the sacrificial layer. The method further includes forming an air gap in the isolation trench under the air gap layer by removing the sacrificial layer after forming the air gap layer

Methodology Applied
Scientific EffectEtching:

Data Source

PatentUS8629035B2Method of manufacturing semiconductor device
Publication Date: 2014.01.14 KIOXIA CORP
  • US8629035B2 patent drawing
  • US8629035B2 patent drawing
  • US8629035B2 patent drawing

AI summary

In one embodiment, a method of manufacturing a semiconductor device includes forming an isolation trench in a substrate, and forming an amorphous layer on a sidewall surface of the isolation trench. The method further includes forming a sacrificial layer in the isolation trench via the amorphous layer, and forming an air gap layer on the sacrificial layer. The method further includes forming an air gap in the isolation trench under the air gap layer by removing the sacrificial layer after forming the air gap layer.