Amorphous Metal Alloy Component Production via Powder Sintering

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Solution Overview

Problem

Current methods for producing amorphous metal alloy components are limited by their inability to create large, complex shapes with homogeneous physical properties, as they require high cooling rates that are technically and economically infeasible, and often result in uneven crystalline phase distribution due to local melting and cooling.

Innovation Solution

A method involving spherical amorphous metal alloy powder with specific particle size and shape, pressed and sintered at temperatures between the transformation and crystallization temperatures to achieve an amorphous content of at least 85%, using vacuum or inert gas environments to minimize crystallization and ensure high bulk density and homogeneity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If conventional quenching methods are used to produce amorphous metal components, then thin layers and compact components can be manufactured, but only components with small cross-sections (a few millimeters) can be produced

Engineering Contradiction:
Improvecomponent volumeVSAvoidmanufacturability of large components
Core Design Contradiction:
Volume of moving objectVSEase of manufacture

Solution Approach 1:

The component is divided into layered structures where each layer is formed by depositing amorphous metal powder and selectively removing material. This segmentation allows large-volume components to be constructed from manageable layers, overcoming the size limitation of conventional quenching methods while maintaining the amorphous structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from bulk material processing to layer-by-layer construction in the vertical dimension. By building components layer by layer from powder deposits and selectively removing material, the method enables production of large-volume components with complex geometries that would be impossible with traditional quenching techniques.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Volume of moving object

If electron beam melting is used to build components from amorphous powder, then larger components can be produced, but the process becomes very complex and expensive

Engineering Contradiction:
Improvecomponent volumeVSAvoidprocess complexity
Core Design Contradiction:
Volume of moving objectVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the complex electron beam melting step from the process. Instead of melting powder layers with electron beams, the method uses simple powder deposition followed by selective material removal, dramatically reducing equipment complexity and cost while achieving the same goal of producing large amorphous components.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces expensive, complex electron beam equipment with simple, inexpensive powder deposition and material removal processes. The use of readily available amorphous metal powder and basic machining operations substitutes for costly specialized equipment, making the process economically viable.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Volume of moving object

If local melting and cooling of powder is performed, then components can be built layer by layer, but homogeneous distribution of physical properties cannot be achieved

Engineering Contradiction:
Improvecomponent volumeVSAvoidhomogeneity of physical properties
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

The amorphous metal powder is prepared in advance with controlled particle size distribution (predominantly 5-12 μm) and stored in an inert atmosphere to prevent oxidation before deposition. This preliminary preparation ensures that the powder maintains its amorphous structure and uniform properties throughout the layer-by-layer construction process, achieving homogeneous physical properties in the final component.

Inventive Principle:
Principle #10Preliminary action

4Volume of moving object

If amorphous metal powder is used for component production, then large components can be manufactured, but crystalline phases form if cooling rate is too slow

Engineering Contradiction:
Improvecomponent volumeVSAvoidamorphous phase stability
Core Design Contradiction:
Volume of moving objectVSStability of the object's composition

Solution Approach 1:

The invention changes the critical parameter of cooling rate by using extremely fine amorphous metal powder particles (5-12 μm) with high surface area to volume ratio. This particle size parameter change enables rapid cooling during deposition and drying, preventing crystallization and maintaining the amorphous phase stability in large-volume components that would otherwise crystallize with slow cooling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The entire process of powder handling, deposition, and drying is conducted in an inert atmosphere (argon or nitrogen) to prevent oxidation and thermal degradation of the amorphous powder. This inert environment protects the metastable amorphous phase from transforming into crystalline structures during the layer-by-layer construction process.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of large, complex components with a high proportion of amorphous phase, achieving near-net-shape production with low porosity and high reproducibility, while minimizing crystalline phases and maintaining the amorphous character of the alloy.

Implementation Method 1

Compaction and sintering of the powder by heat treatment of the powder during or after pressing at a temperature between the transformation temperature and the crystallization temperature of the amorphous phase of the metal alloy

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

heat treatment of the powder during or after pressing at a temperature between the transformation temperature and the crystallization temperature of the amorphous phase

Methodology Applied
Scientific EffectGlass transition: Phase Change

Data Source

PatentEP2944401B1Method for producing a component from a metallic alloy containing an amorphous phase
Publication Date: 2019.03.13 HERAEUS DEUTSCHLAND GMBH & CO KG
  • EP2944401B1 patent drawing
  • EP2944401B1 patent drawing
  • EP2944401B1 patent drawing

AI summary

The invention relates to a method for producing a component from an at least partially amorphous metal alloy, comprising the steps of: providing a powder from an at least partially amorphous metal alloy, wherein the powder consists of spherical powder particles and the powder particles have a diameter of less than 125 µm; pressing the powder into the desired shape of the component to be produced; compacting and sintering the powder by heat treatment of the powder during or after pressing at a temperature that lies between the transformation temperature and the crystallization temperature of the amorphous phase of the metal alloy, wherein the duration of the heat treatment is selected such that the component is sintered after the heat treatment and has an amorphous content of at least 85 percent.The invention also relates to a component made of a pressed, sintered, spherical, amorphous metal alloy powder, wherein the component has an amorphous content of at least 85 percent, and the use of such a component as a gear, friction wheel, wear-resistant component, housing, watch case, part of a transmission or semi-finished product.