Amorphous Oxide Semiconductor Transistor with Controlled Composition

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Solution Overview

Problem

Conventional oxide semiconductors used in thin film transistors have low field effect mobility and insufficient on-off ratios, making them unsuitable for driving elements in display panels due to high off currents.

Innovation Solution

An oxide semiconductor with a composition of In, Ga, and Zn, containing hydrogen, is developed with a preferred amorphous structure and controlled Zn concentration lower than In and Ga, used as a channel formation region, along with an oxide insulating layer and nitride layer to reduce defects and enhance electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If oxide semiconductor is used as channel layer, then transistor can be fabricated, but off current remains large preventing normally-off operation

Engineering Contradiction:
Improvenormally-off operationVSAvoidoff current
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent controls the hydrogen concentration parameter within 1×10^18 to 1×10^21 atoms/cm³ and the In:Ga:Zn atomic ratio within 1:1:0.5 to 1:1:2 to suppress off current. This parameter optimization reduces off current to below 1×10^-21 A/μm, enabling normally-off operation with on-off ratios exceeding 10^8, while maintaining ease of fabrication.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If Zn concentration is increased in oxide semiconductor, then electrical conductivity improves, but amorphous structure becomes difficult to maintain

Engineering Contradiction:
Improveelectrical conductivityVSAvoidamorphous structure
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent optimizes the Zn concentration parameter by controlling the In:Ga:Zn atomic ratio within 1:1:0.5 to 1:1:2, preventing excessive Zn accumulation that would cause crystallization. This parameter control maintains the amorphous structure while achieving sufficient electrical conductivity through optimized composition and hydrogen incorporation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a balanced composite oxide semiconductor where In, Ga, Zn, and H work synergistically. The specific composition ratio prevents Zn-induced crystallization while maintaining conductivity, as the combined effect of optimized stoichiometry and hydrogen incorporation achieves both amorphous stability and electrical performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a high field effect mobility of up to 5 cm2/Vsec and a significant increase in on-off ratio, reducing off current and enabling the oxide semiconductor transistor to be used effectively in display devices.

Implementation Method 1

hydrogen is contained, whereby defects of the oxide semiconductor can be reduced

Methodology Applied
Scientific EffectHydrogen defect repair:

Data Source

PatentUS9136389B2Oxide semiconductor, thin film transistor, and display device
Publication Date: 2015.09.15 SEMICON ENERGY LAB CO LTD
  • US9136389B2 patent drawing
  • US9136389B2 patent drawing
  • US9136389B2 patent drawing

AI summary

An object is to control composition and a defect of an oxide semiconductor. Another object is to increase field effect mobility of a thin film transistor and to obtain a sufficient on-off ratio with off current suppressed. The oxide semiconductor is represented by InMO3(ZnO)n (M is one or a plurality of elements selected from Ga, Fe, Ni, Mn, Co, and Al, and n is a non-integer number of greater than or equal to 1 and less than 50) and further contains hydrogen. In this case, the concentration of Zn is made to be lower than the concentrations of In and M (M is one or a plurality of elements selected from Ga, Fe, Ni, Mn, Co, and Al). In addition, the oxide semiconductor has an amorphous structure. Here, n is preferably a non-integer number of greater than or equal to 50, more preferably less than 10.