Amorphous Polymeric Foam Nucleating Agent Thermal Conductivity
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Solution Overview
Problem
The transition from hydrochlorofluorocarbon (HCFC) foam blowing agents to carbon dioxide and hydrocarbons has resulted in increased thermal conductivity of insulation foams, leading to a loss of thermal resistance and failure to meet product specifications, necessitating additional measures to enhance insulation properties.
Innovation Solution
A composition comprising at least 80% by weight of an essentially amorphous polymer, such as polystyrene, combined with a nucleating agent of specific formula, which reduces cell size and improves mechanical and thermal insulation properties of polymeric foams.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-affected harmful factors
If carbon dioxide and hydrocarbons are used as foam blowing agents instead of HCFC, then environmental compatibility is improved, but thermal conductivity increases leading to reduced thermal resistance
Solution Approach 1:
The patent applies parameter changes by modifying the physical and chemical parameters of the foam system through the addition of a nucleating agent. This agent changes the cell structure parameters (size, distribution, uniformity) of the foam, which in turn modifies the thermal conductivity parameter. By controlling nucleation density and cell morphology, the thermal resistance is enhanced despite using environmentally friendly blowing agents with higher thermal conductivity.
Solution Approach 2:
The patent creates a composite foam structure by combining the polymer matrix with a specifically engineered cell structure through nucleating agent treatment. This composite approach involves multiple components working together: the environmentally friendly blowing agent provides gas-filled cells, while the nucleating agent creates an optimized cellular architecture that collectively achieves improved thermal insulation performance.
2Loss of energy
If additional steps are taken to increase thermal resistance of insulation foams, then thermal insulation performance is improved, but device complexity and processing steps increase
Solution Approach 1:
The patent merges multiple functions into a single additive component - the nucleating agent simultaneously serves as both a nucleating agent for cell formation and a thermal performance enhancer. This consolidation eliminates the need for separate post-processing steps to improve thermal resistance, as the thermal enhancement is achieved intrinsically during the foam formation process itself.
Solution Approach 2:
The nucleating agent enables the foam system to self-optimize its thermal properties during the foaming process. The agent automatically nucleates cell formation and controls cell structure development without requiring external intervention or additional processing steps. The system self-regulates to achieve the desired cellular morphology and thermal performance through the inherent properties of the nucleating agent.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution achieves a significant reduction in thermal conductivity by approximately 3-10% and enhances mechanical properties like compressive strength and creep resistance, resulting in improved insulation and surface quality of the polymeric foam.
Implementation Method 1
nucleating agent of formula (1)... which reduces cell size and improves mechanical and thermal insulation properties of polymeric foams
Data Source
AI summary
The present invention relates to composition for the preparation of a polymeric foam with improved thermal properties, to a polymeric foam obtainable therefrom, and to a method for preparing such a polymeric foam each for them comprising (i) an at least essentially amorphous polymer resin and (ii) a nucleating agent. The at least essentially amorphous polymer resin is preferably polystyrene. The nucleating agent is preferably selected from the group consisting of 1,3:2,4-bis-(benzylidene)-sorbitol derivates and mixtures thereof, and is preferably 1,3:2,4-bis-O-(4-methylbenzylidene)-D-sorbitol, 1,3:2,4-bis-(3,4-Dimethylbenzylidene)-sorbitol and 1,3:2,4-bis-(4-propylbenzylidene)-propyl sorbitol.


