Amorphous Polymeric Layer Retroreflective Sheeting Shrinkage

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Solution Overview

Problem

Existing retroreflective articles manufactured using the cast and cure method suffer from optical imperfections due to high shrinkage of cube corner elements, leading to reduced retroreflectivity, and require a carrier layer for a low elastic modulus body layer to prevent distortion during processing.

Innovation Solution

Incorporating a substantially amorphous polymeric layer between the crystalline body layer and discrete truncated cube corner elements to absorb and dissipate stress forces during processing, allowing for increased fidelity and brightness of the retroreflective articles without the need for a separate carrier layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If the cast and cure method is used to manufacture retroreflective sheeting, then the manufacturing process is simplified and continuous production is enabled, but the cube corner elements exhibit high shrinkage upon solidifying causing optical imperfections and reduced retroreflectivity

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidcube corner element geometry precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from crystalline polymer to amorphous polymer for the body layer, which eliminates shrinkage upon curing while maintaining the cast and cure manufacturing process. This parameter change resolves the contradiction by allowing continuous production without geometric distortion of the cube corner elements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite structure combining an amorphous polymer body layer with a crystalline overlay layer. The amorphous body layer provides shrinkage-free curing for precise cube corner formation, while the crystalline overlay layer provides mechanical strength and dimensional stability during processing.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If a low elastic modulus body layer is used to achieve high flexibility and cube corner dimensional stability during flexing, then retroreflective performance is maintained, but a carrier layer is required to prevent stretching during winding and unwinding processes

Engineering Contradiction:
Improvesheeting flexibilityVSAvoidnumber of layers required
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent changes the elastic modulus parameter of the body layer by using an amorphous polymer with appropriately controlled properties. This allows the body layer to have sufficient flexibility for retroreflective performance while maintaining enough rigidity to withstand processing without a separate carrier layer.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If stress forces during cast and cure processing are reduced to maintain cube corner fidelity, then retroreflectivity is improved, but the structural integrity and handling of the sheeting during processing becomes difficult

Engineering Contradiction:
Improvecube corner element fidelityVSAvoidsheeting structural integrity
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent employs a composite structure where the amorphous polymer body layer provides a stress-absorbing, flexible matrix that protects cube corner elements during processing, while the crystalline overlay layer provides the necessary structural integrity and mechanical strength for handling.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The amorphous polymer body layer acts as an intermediary between the cube corner elements and the processing environment, absorbing stress forces and protecting the delicate optical structures while allowing the sheeting to be handled during manufacturing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amorphous polymeric layer enhances the brightness and dimensional stability of retroreflective articles, maintaining retroreflective efficiency and flexibility while reducing manufacturing costs and complexity.

Implementation Method 1

the substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the article during processing

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 2

Cube corner reflecting elements include generally trihedral structures that have three approximately mutually perpendicular lateral faces meeting in a single corner--a cube corner. In use, the retroreflector is arranged with the front surface disposed generally toward the anticipated location of intended observers and the light source. Light incident on the front surface enters the sheet and passes through the body of the sheet to be reflected by each of the three faces of the elements, so as to exit the front surface in a direction substantially parallel to the light source.

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Data Source

PatentEP3036097B1Retroreflective sheeting including a substantially amorphous polymeric layer
Publication Date: 2020.09.23 3M INNOVATIVE PROPERTIES CO
  • EP3036097B1 patent drawingFigure 1~4

AI summary

The present application generally relates to retroreflective articles and methods of making retroreflective articles. The retroreflective articles include a substantially amorphous polymeric layer between the body layer and the discrete truncated cube corner elements. The substantially amorphous polymeric layer absorbs, dissipates, and/or accommodates at least some of the stress forces placed on the retroreflective article during processing. As a result, discrete truncated cube corner elements with increased fidelity can be formed. Consequently, retroreflective sheeting including a substantially amorphous polymeric layer has increased brightness compared to similarly made and composed sheeting lacking the substantially amorphous polymeric layer