Amorphous Silicon Fluorine Doping With a Conductive Protective Layer

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Solution Overview

Problem

Conventional fluorine doping processes in display device manufacturing generate static electricity, leading to positive shifts in threshold voltage due to local F+ ion concentration, which affects the performance of transistors.

Innovation Solution

A method involving the formation of a conductive protective layer on amorphous silicon before fluorine doping, which prevents static electricity generation by maintaining the same potential as the silicon and removing fluorine after doping, ensuring it does not remain on the silicon surface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If fluorine doping is performed directly on amorphous silicon without a protective layer, then doping efficiency is improved, but static electricity is generated causing positive shifts in threshold voltage

Engineering Contradiction:
Improvedoping precisionVSAvoidstatic electricity
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

A conductive protective layer is introduced as an intermediary between the fluorine doping process and the amorphous silicon. This protective layer acts as a mediator that prevents direct charge accumulation on the silicon surface while still allowing fluorine ions to pass through and dope the underlying insulating film, thus eliminating static electricity generation without compromising doping efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The conductive protective layer is formed on the amorphous silicon surface before the fluorine doping process begins. This preliminary action prepares the surface by establishing a conductive pathway that prevents charge accumulation during subsequent doping, thereby preventing static electricity generation before it can occur

Inventive Principle:
Principle #10Preliminary action

2Object-generated harmful factors

If a conductive protective layer is formed before fluorine doping, then static electricity generation is prevented, but additional process steps are required

Engineering Contradiction:
Improvestatic electricityVSAvoidprocess complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The conductive protective layer serves multiple functions simultaneously: it acts as a protective barrier during doping, provides a conductive pathway to prevent static electricity, and can be integrated with existing electrode structures in the display device. This multi-functionality reduces the need for separate dedicated components and minimizes overall process complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Productivity

If fluorine remains on the silicon surface after doping, then doping efficiency is maintained, but transistor performance is degraded due to threshold voltage shift

Engineering Contradiction:
Improvedoping efficiencyVSAvoidtransistor performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The conductive protective layer serves as an intermediary that controls fluorine distribution during doping. It allows fluorine ions to pass through and dope the insulating film effectively, but prevents excess fluorine from accumulating on the silicon surface, thus maintaining doping efficiency while protecting transistor performance

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The conductive protective layer is removed after the fluorine doping process is complete. This extraction step eliminates any remaining fluorine on the silicon surface that could cause threshold voltage shifts, while the doping of the insulating film has already been accomplished during the process

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach prevents static electricity generation during fluorine doping, minimizing defects in the insulating film and maintaining the integrity of the transistor performance by avoiding positive shifts in threshold voltage.

Implementation Method 1

forming a conductive protective layer on the amorphous silicon before doping with fluorine, which prevents static electricity generation by maintaining the same potential as the silicon

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

doping with fluorine... By the fluorine doping, fluorine may be doped into an insulating layer positioned under the amorphous silicon

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 3

Removing the conductive protective layer may be performed by wet etching

Methodology Applied
Scientific EffectWet etching:

Data Source

PatentUS20250017055A1Display device and manufacturing method thereof
Publication Date: 2025.01.09 SAMSUNG DISPLAY CO LTD
  • US20250017055A1 patent drawing
  • US20250017055A1 patent drawing
  • US20250017055A1 patent drawing

AI summary

A method of manufacturing a display device according to an embodiment of the present invention includes forming amorphous silicon on a substrate and forming a conductive protective layer on the amorphous silicon, doping with fluorine and removing the conductive protective layer.