Amphiphilic Co-polymer Conjugates for Controlled Fragrance Release

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Solution Overview

Problem

The perfume industry faces challenges in prolonging the effect of volatile or poorly substantive perfuming ingredients, with existing polymer-based solutions offering modest performance in releasing active molecules effectively.

Innovation Solution

Development of amphiphilic co-polymer conjugates based on a polyethylene or polypropylene backbone with β-oxy or β-thio carbonyl moieties, capable of releasing odoriferous molecules like α,β-unsaturated ketones, aldehydes, or carboxylic esters, through controlled decomposition reactions, enhancing perfume release and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If existing polymer-based solutions (styrene co-polymers) are used to prolong the effect of perfuming ingredients, then the duration of action is extended, but the release performance of active molecules remains modest

Engineering Contradiction:
Improveduration of perfume effectVSAvoidrelease performance
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent modifies the chemical structure of polymer-based pro-fragrances by incorporating specific β-oxy carbonyl or β-thio carbonyl moieties into the polymer backbone. This structural parameter change enables controlled decomposition reactions that selectively release odoriferous molecules, transforming the modest release performance into superior controlled release while maintaining prolonged duration of action.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite polymer structures combining hydrophobic segments (for substantivity and prolonged effect) with hydrophilic β-oxy or β-thio carbonyl moieties (for controlled release). This composite approach integrates the advantages of both hydrophobic and hydrophilic characteristics, achieving both extended duration and improved release performance simultaneously.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If volatile perfuming ingredients are used to provide immediate fragrance, then the intensity is high, but the substantivity and duration are poor

Engineering Contradiction:
Improvefragrance intensityVSAvoidsubstantivity
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent incorporates odoriferous molecules into the polymer structure during the polymerization process, creating a pre-assembled pro-fragrance system. The odoriferous molecules are trapped within the polymer matrix in advance, allowing them to be released gradually over time. This preliminary incorporation ensures both immediate fragrance intensity upon application and prolonged substantivity through controlled decomposition and release mechanisms.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The co-polymer conjugates provide superior performance in releasing odoriferous molecules, offering improved substantivity and prolonged fragrance retention on surfaces such as textiles and hair, outperforming previous polymer-based solutions.

Implementation Method 1

capable of liberating an active molecule such as, for example, an α,β-unsaturated ketone, aldehyde or carboxylic ester through controlled decomposition reactions

Methodology Applied
Scientific EffectDecomposition reaction: Decomposition (biological)

Implementation Method 2

improved substantivity and prolonged fragrance retention on surfaces such as textiles and hair

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS8383750B2Amphiphilic co-polymer conjugates for a controlled release of active molecules
Publication Date: 2013.02.26 FIRMENICH SA
  • US8383750B2 patent drawing
  • US8383750B2 patent drawing
  • US8383750B2 patent drawing

AI summary

The present invention relates to the field of perfumery. More particularly, it concerns polyethylene or polypropylene based polymers that have at least one β-oxy or β-thio carbonyl moiety capable of liberating a perfuming molecule such as, for example, an α,β-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of such compounds in perfumery as well as the perfuming compositions or perfumed articles that include such compounds.