Amphoteric Polymer Blend for Paper Strength in High-Conductivity Papermaking

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing paper-strengthening agents fail to effectively enhance paper strength in high electrical conductivity papermaking environments, leading to reduced paper quality due to interference from calcium ions and formation of insoluble polyion complexes.

Innovation Solution

A paper-strengthening agent comprising a mixture of two amphoteric (meth)acrylamide polymers with specific viscosity ratios and molecular weights, forming a polyion complex to enhance paper strength even in high electrical conductivity conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single amphoteric (meth)acrylamide polymer is used as paper-strengthening agent, then the agent can function in low electrical conductivity environments, but the paper-strengthening effect is insufficient in high electrical conductivity environments due to ion shielding by calcium ions

Engineering Contradiction:
Improvepaper-strengthening effectVSAvoidadaptability to electrical conductivity conditions
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent divides the single polymer into two different amphoteric (meth)acrylamide polymers with different molecular weights (first polymer with weight-average molecular weight of 1,500,000 to 10,000,000 and second polymer with weight-average molecular weight of 1,500,000 to 10,000,000 but different viscosity characteristics). This segmentation allows each polymer to contribute differently to the overall performance, with the mixture providing both low-viscosity flowability and high-viscosity strengthening effects, thereby achieving reliable paper-strengthening across varying electrical conductivity conditions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent creates a composite paper-strengthening agent by combining two different amphoteric (meth)acrylamide polymers in a specific ratio (first polymer:second polymer by weight is 95:5 to 50:50). This composite formulation leverages the complementary properties of both polymers to achieve superior performance in high electrical conductivity environments where single polymers fail, while maintaining effectiveness in low conductivity environments as well.

Inventive Principle:
Principle #40Composite materials

2Strength

If the viscosity of the paper-strengthening agent is high to ensure paper strength, then paper strength improves, but cloudiness and insoluble substance formation increase in high electrical conductivity environments

Engineering Contradiction:
Improvepaper strengthVSAvoidcloudiness and insoluble substance formation
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent segments the viscosity contribution into two separate polymers with different viscosity characteristics. The first polymer provides base viscosity and strengthening, while the second polymer (with higher viscosity at lower concentrations) provides enhanced strengthening only when needed. This segmentation prevents excessive viscosity buildup that would cause cloudiness and insoluble substance formation, while still achieving adequate paper strength.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the viscosity parameter dynamically through the mixture ratio of the two polymers. By adjusting the ratio of first polymer to second polymer (95:5 to 50:50), the overall viscosity of the paper-strengthening agent can be optimized to provide sufficient strength without excessive viscosity that would cause harmful effects like cloudiness and insoluble substance formation in high electrical conductivity environments.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If amphoteric (meth)acrylamide polymer is used in high electrical conductivity papermaking systems, then the agent attempts to compensate for strength loss, but the ion portion is shielded by dissolved electrolyte such as calcium ion, reducing effectiveness

Engineering Contradiction:
Improvepaper-strengthening effectVSAvoidion shielding by calcium ions
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent segments the polymer population into two distinct molecules with different molecular weights and viscosity characteristics. This segmentation creates a more versatile agent that can navigate high electrical conductivity environments better, as the mixture provides both low-viscosity components that can access ion sites and high-viscosity components that provide structural strengthening, thereby compensating for ion shielding effects.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent formulates a composite paper-strengthening agent combining two amphoteric (meth)acrylamide polymers in specific ratios (95:5 to 50:50 by weight). This composite material leverages the synergistic effects of both polymers to overcome ion shielding by calcium ions, providing sufficient paper-strengthening effect in high electrical conductivity environments where single polymers are ineffective.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The agent provides excellent paper-strengthening effects in both low and high electrical conductivity environments, preventing cloudiness and insoluble substance formation, and ensuring uniform paper quality.

Implementation Method 1

The amphoteric type (meth)acrylamide-based polymer is obtained by copolymerizing acrylamide with various polymerization components such as a cationic monomer and an anionic monomer. The (meth)acrylamide-based polymer has an isoelectric point and forms a polyion complex (hereinafter, referred to as 'PIC') at a pH near the isoelectric point. When PIC is formed, a phenomenon of cloudiness is observed.

Methodology Applied
Scientific EffectIonic bonding: Chemical Bonding

Implementation Method 2

the present inventors have found that a paper-strengthening agent can be provided by which paper exhibiting an excellent paper-strengthening effect can be obtained not only in a papermaking environment with a low electrical conductivity (less than 3 mS/cm) but also in a papermaking environment with a high electrical conductivity (3 mS/cm or more), when a viscosity upon mixing of a plurality of amphoteric (meth)acrylamide-based polymers is equal to or greater than an arithmetic mean of a value indicated by each polymer

Methodology Applied
Scientific EffectViscosity increase: Viscoelasticity

Data Source

PatentUS12448734B2Paper-strengthening agent, paper, and method of producing paper
Publication Date: 2025.10.21 ARAKAWA CHEM IND LTD

AI summary

A paper-strengthening agent comprising an amphoteric (meth)acrylamide polymer and an amphoteric (meth)acrylamide polymer, wherein each of constituent monomers of the amphoteric (meth)acrylamide polymer and the amphoteric (meth)acrylamide polymer comprises (meth)acrylamide, a cationic unsaturated monomer, an anionic unsaturated monomer, and a crosslinkable unsaturated monomer, and has a specific weight-average molecular weight, and wherein each viscosity of the paper-strengthening agent, the polymer, and the polymer satisfies a specific relationship.