Amphoteric Surfactant-Dye Complex for Hair Color Fastness

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Solution Overview

Problem

Current hair dyes, particularly direct dyes, face challenges in achieving uniform and long-lasting color on hair with varying degrees of damage, as they often result in uneven coloring and rapid discoloration due to insufficient fastness properties, especially when exposed to washing and external influences like sunlight or swimming pool water.

Innovation Solution

A hair dye formulation combining cationic anthraquinone dyes with amphoteric surfactants, specifically alkyl amphodiacetate and/or alkyl amphodipropionate, which provides improved fastness and leveling properties, ensuring consistent color retention even after repeated washing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If direct dyes are used for hair coloring, then the coloring process is gentler on the fiber, but the fastness properties are insufficient especially against washing and external influences

Engineering Contradiction:
Improvefiber damage from oxidizing agentsVSAvoidfastness properties of dye
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent combines direct dyes with amphoteric surfactants to create a composite coloring composition. The amphoteric surfactant forms a complex with the direct dye on the hair fiber, creating a composite structure that enhances fastness properties while maintaining the gentleness of direct dyeing. This composite approach allows the dye-surfactant complex to resist washing and external influences better than direct dyes alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The amphoteric surfactant acts as an intermediary between the direct dye and the hair fiber. It facilitates the deposition of the dye onto the fiber while providing additional functionality through its surfactant properties. The surfactant mediates the interaction between the dye and fiber, improving adhesion and fastness without requiring harsh oxidizing agents.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If direct dyes are used, then the application conditions are gentler, but the dyes are much more sensitive to shampooing causing rapid discoloration

Engineering Contradiction:
Improveapplication conditionsVSAvoidcolor retention after shampooing
Core Design Contradiction:
Ease of operationVSDuration of action of stationary object

Solution Approach 1:

The patent creates a composite system where direct dyes are combined with amphoteric surfactants. This composite structure on the hair fiber provides both the ease of direct dye application and improved resistance to shampooing. The surfactant component of the composite binds to the fiber and anchors the dye, reducing sensitivity to washing.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If direct dyes are applied to pre-treated hair with varying damage, then the coloring process is simpler, but uneven coloring occurs due to varying degrees of damage at different areas

Engineering Contradiction:
Improvecoloring process complexityVSAvoiduniformity of color distribution
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The amphoteric surfactant in the composition provides local adaptation to different hair conditions. It can interact with varying degrees of fiber damage at different areas, adjusting its binding characteristics locally. This allows uniform color distribution even on pre-treated hair with varying damage, as the surfactant-dye complex adapts to local fiber properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes changes in the physical-chemical parameters of the dyeing composition by incorporating amphoteric surfactants. These surfactants can change their behavior based on local conditions (pH, ionic strength, fiber condition), allowing the composition to adapt to varying hair damage levels and achieve uniform coloring without complex processing steps.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of cationic anthraquinone dyes with amphoteric surfactants results in brilliant, intensive, and uniform color that maintains its fastness and shine, addressing the issues of uneven coloring and rapid discoloration associated with traditional hair dyes.

Implementation Method 1

combinations of certain cationic anthraquinones as direct dyes with certain amphoteric surfactants lead to colorations that solve the task to an outstanding degree

Methodology Applied
Scientific EffectElectrostatic interaction: Ion Repulsion/Attraction

Data Source

PatentEP2794024B2Coloring agent comprising direct dyes and amphoteric surfactants
Publication Date: 2023.03.01 HENKEL KGAA
  • EP2794024B2 patent drawing
  • EP2794024B2 patent drawing
  • EP2794024B2 patent drawing

AI summary

The invention relates to a substance for dyeing keratin fibers, containing (a) at least one compound of formula (I), and (b) at least one amphoteric surfactant.