Anaerobic Fermentation Column Reactor for Biofuel Separation

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Solution Overview

Problem

Current biological processes for producing biofuels like lipids and hydrocarbons face challenges in scalability, cost, and efficiency, particularly in separating the products from fermentation broths without external electron acceptors like oxygen, leading to inefficient carbon dioxide and gas production, and requiring complex separation techniques.

Innovation Solution

A continuous anaerobic fermentation process using micro-organisms in a column reactor with upward flowing aqueous medium, where fermentation gas is separated prior to product separation, promoting coalescence using SLL separation techniques like gravity settling, flotation, or hydrocyclones, and tilted plate separators, to enhance the recovery of lipids or hydrocarbons as a separate liquid phase.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional stirred fermentors with centrifugal separation are used, then product separation is achieved, but capital investment and energy costs are high

Engineering Contradiction:
Improvemanufacturing costVSAvoidseparation efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The fermentation process is segmented into distinct zones within the column reactor: an anaerobic fermentation zone at the bottom and an aerobic oxidation zone at the top. This segmentation allows simultaneous product formation and gas separation, eliminating the need for separate centrifugal separation equipment and reducing capital investment while maintaining high productivity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The column reactor performs multiple functions simultaneously: it serves as both the fermentation vessel and the gas-liquid separation device. The upward flow of aqueous medium through the packed bed enables both substrate delivery to microorganisms and efficient gas removal, consolidating what would traditionally require separate equipment into a single integrated system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of manufacture

If anaerobic fermentation without external electron acceptor is used, then fuel purification costs are reduced, but fermentation gas production requires complex mixing devices

Engineering Contradiction:
Improvepurification costVSAvoidmixing device complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The system uses the fermentation gas produced during anaerobic fermentation as the driving force for its own circulation and separation. The gas generated by microorganisms naturally flows upward through the packed bed, carrying aqueous medium and product droplets to the oxidation zone, eliminating the need for external mixing devices or mechanical agitation systems.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The process utilizes pneumatic principles where fermentation gas flow drives the circulation of aqueous medium through the column reactor. The gas-liquid flow dynamics naturally achieve mixing and mass transfer functions that would otherwise require mechanical devices, simplifying the overall system architecture.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Productivity

If fermentation gas is produced in substantial amounts, then turbulent mixing is achieved without separate mixing devices, but gas-liquid separation becomes more difficult

Engineering Contradiction:
Improvemixing efficiencyVSAvoidseparation equipment complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The reactor is divided into anaerobic and aerobic zones, with the aerobic zone specifically designed for gas-liquid separation. The packed bed structure in the oxidation zone provides large surface area for gas absorption and liquid redistribution, efficiently separating fermentation gas from the aqueous medium without requiring additional separation equipment.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process transitions from horizontal mixing in a stirred tank to vertical countercurrent flow in a column reactor. The upward flow of liquid and downward flow of gas create efficient mass transfer and separation in the vertical dimension, utilizing the packed bed structure to achieve both mixing and separation functions simultaneously.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Ease of manufacture

If upflow packed bed column reactor is used, then investment costs are reduced, but product coalescence and separation require optimized conditions

Engineering Contradiction:
Improveinvestment costVSAvoidseparation precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The process optimizes several parameters to achieve effective product separation: controlling the upward flow rate of aqueous medium, adjusting the packed bed height and particle size, and regulating the gas flow rate. These parameter changes create optimal conditions for droplet coalescence and phase separation in the oxidation zone without requiring complex or expensive equipment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables a cost-effective, integrated bioreactor system for direct production of biofuels from renewable sources, reducing investment and operational costs by minimizing surplus cell mass and using inexpensive reactor materials, while achieving high yields and efficient separation of biofuels without the need for separate mixing devices or expensive equipment.

Implementation Method 1

separating the product from each other under conditions that coalescence of the product is promoted, wherein the fermentation gas is at least partly separated from the aqueous medium prior to separating the product from the aqueous phase wherein SLL (i.e. solid-liquid-liquid) separation techniques are used for promoting the coalescence of the product droplets

Methodology Applied
Scientific EffectFlotation: Froth Floatation

Implementation Method 2

SLL separation techniques including gravity settling, flotation or a combination thereof

Methodology Applied
Scientific EffectGravity settling: Sedimentation

Data Source

PatentEP2196539B1Process for the continuous biological production of lipids, hydrocarbons or mixtures thereof
Publication Date: 2022.02.09 DELFT ADVANCED BIOFUELS BV
  • EP2196539B1 patent drawingFigure 1~2
  • EP2196539B1 patent drawingFigure 3
  • EP2196539B1 patent drawing

AI summary

The present invention is directed to a process for the continuous biological production of lipids, hydrocarbons, hydrocarbon like material or mixtures thereof by conversion of a suitable substrate using micro-organisms, in which process the said substrate is continuously, anaerobically fermented to produce lipids, hydrocarbons, hydrocarbon like material or mixtures thereof and fermentation gas, in the presence of, optionally supported, micro-organisms in an aqueous medium in a column type reactor, in which reactor at least part of the aqueous medium flows in upward direction, and recovering the lipids, hydrocarbon or hydrocarbon like material by separating the fermentation gas, the micro-organisms, the lipids, hydrocarbon or hydrocarbon like material from each other under conditions that coalescence of the hydrocarbon material or hydrocarbon like material is promoted.