Anhydrous Oral Care Composition Using Peroxymonosulfate

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Solution Overview

Problem

Existing oral care compositions using hydrogen peroxide for teeth whitening face issues with irritation, instability in aqueous environments, and difficulty in creating homogeneous non-aqueous structures, limiting the use of alternative oxidizing agents like peroxysulfuric acid or peroxysulfates.

Innovation Solution

A non-aqueous oral care composition incorporating potassium peroxymonosulfate as a whitening agent, combined with a polyvinylpyrrolidone/vinyl acetate copolymer and specific non-aqueous dispersants such as triacetin, which stabilizes the oxidizing agent and maintains homogeneity, avoiding hydrogen peroxide and high water content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen peroxide is used as a whitening agent in high concentrations, then whitening efficacy is improved, but irritation to teeth and gums increases and stability decreases

Engineering Contradiction:
Improvewhitening efficacyVSAvoidirritation to teeth and gums
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter from hydrogen peroxide to peroxymonosulfate, which has different stability and reactivity characteristics. This allows achieving whitening efficacy while reducing irritation and improving stability in non-aqueous environments

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a non-aqueous environment (inert relative to peroxide stability) to prevent decomposition of the oxidizing agent. By eliminating water, the system achieves enhanced stability while maintaining whitening efficacy

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Stability of the object's composition

If alternative oxidizing agents like peroxysulfuric acid or peroxysulfates are used, then stability in non-aqueous environments is improved, but difficulty in creating homogeneous structures increases

Engineering Contradiction:
Improvestability in non-aqueous environmentsVSAvoidhomogeneity of composition
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent introduces a surfactant as an intermediary substance that facilitates uniform distribution of peroxymonosulfate in the non-aqueous medium. The surfactant acts as a mediator between the oxidizing agent and the non-aqueous vehicle, enabling homogeneous structure formation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system combining peroxnymonosulfate, non-aqueous vehicle, and surfactant. This composite approach allows achieving both stability and homogeneity by leveraging the complementary properties of each component

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If peroxymonosulfate is used with non-aqueous liquids, then stability is improved, but difficulty in creating homogeneous structures persists

Engineering Contradiction:
Improveproduct stabilityVSAvoidhomogeneity
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The surfactant serves as a mediator that enables compatible interaction between peroxnymonosulfate and non-aqueous liquids, resolving the incompatibility issue and achieving homogeneous mixing while maintaining stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves stable and effective teeth whitening with enhanced stability and homogeneity, outperforming hydrogen peroxide-based gels in whitening efficacy and maintaining product stability.

Implementation Method 1

Alternative oxidizing agents, such as peroxysulfuric acid or peroxysulfates, have been used as stain removing agents

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

combined with a polyvinylpyrrolidone/vinyl acetate copolymer and specific non-aqueous dispersants such as triacetin, which stabilizes the oxidizing agent and maintains homogeneity

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentEP3532021B1Anhydrous oral care composition
Publication Date: 2023.06.07 COLGATE PALMOLIVE CO
  • EP3532021B1 patent drawingFigure 1
  • EP3532021B1 patent drawingFigure 2
  • EP3532021B1 patent drawing

AI summary

An oral care composition, including a peroxysulfate whitening agent, a non-aqueous dispersant having a non-aqueous liquid, and a structural builder.