Anionic Latex Encapsulation for Sustained Antimicrobial Release

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Solution Overview

Problem

Existing latex polymer coatings with antimicrobial agents often fail to provide long-term protection, especially against fungi, and face challenges in controlling and enhancing antimicrobial activity, with regulatory issues and degradation concerns.

Innovation Solution

Incorporating active ingredients during the emulsion polymerization process to create anionic latex polymers that encapsulate and sustain the active agents, allowing for higher concentrations and improved distribution within the polymer matrix, thereby providing enhanced and controlled antimicrobial protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If antimicrobial agents are added to latex after polymerization as formulating ingredients, then the latex formulation can provide antimicrobial properties, but the protection duration is insufficient and long-term protection cannot be achieved

Engineering Contradiction:
Improveantimicrobial protection effectivenessVSAvoidprotection duration
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The antimicrobial agent is incorporated into the latex polymer during the emulsion polymerization process rather than being added afterward. This preliminary incorporation ensures the agent is embedded within the polymer matrix from the beginning, enabling sustained release and long-term antimicrobial protection throughout the service life of the coating

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The antimicrobial agent is nested within the latex polymer matrix during polymerization. The agent becomes encapsulated within the polymer structure, creating a reservoir that releases the active ingredient gradually over time, thereby extending the duration of antimicrobial activity

Inventive Principle:
Principle #7Nested doll (Nesting)

2Reliability

If antimicrobial components are employed in small amounts as formulating ingredients, then the latex formulation can be made, but the extent of antimicrobial protection cannot be sufficiently enhanced or controlled

Engineering Contradiction:
Improveantimicrobial protection effectivenessVSAvoidcontrol of antimicrobial activity
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The amount and concentration of antimicrobial agent can be precisely controlled during the polymerization process by adjusting the feed rate and concentration in the monomer mixture. This enables tailoring the antimicrobial activity level to match specific application requirements, providing both enhanced effectiveness and controllable adaptation to different uses

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The emulsion polymerization process serves multiple functions: it synthesizes the latex polymer while simultaneously incorporating and distributing the antimicrobial agent uniformly throughout the matrix. This multi-functionality ensures both sufficient enhancement of antimicrobial protection and consistent control across different formulations

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of manufacture

If antimicrobial components are added after polymerization, then the latex formulation can be prepared, but regulatory issues arise and the effectiveness cannot be prolonged

Engineering Contradiction:
Improveformulation simplicityVSAvoideffectiveness duration
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The polymerization process and antimicrobial agent incorporation are merged into a single integrated process. The agent is added to the monomer mixture before polymerization begins, combining the benefits of simple formulation (single-step process) with extended effectiveness (sustained release from embedded agent), eliminating the need for separate addition steps

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If traditional blending methods are used to incorporate antimicrobial agents, then the latex formulation can be made, but homogeneous distribution and superior sustained performance cannot be achieved

Engineering Contradiction:
Improveantimicrobial performanceVSAvoiddistribution uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The emulsion polymerization process ensures homogeneous distribution of the antimicrobial agent throughout the latex polymer matrix. The agent is incorporated uniformly during the polymerization reaction, creating consistent spacing and concentration throughout the material, which enables reliable and sustained antimicrobial performance without aggregation or uneven distribution

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the creation of latex polymers with sustained and effective antimicrobial protection, capable of encapsulating large amounts of active ingredients, including hydrophobic components, and offering superior performance compared to traditional methods.

Implementation Method 1

Incorporating active ingredients during the emulsion polymerization process to create anionic latex polymers that encapsulate and sustain the active agents

Methodology Applied
Scientific EffectEncapsulation: Physical Containment

Data Source

PatentEP2279227B1Anionic latex as a carrier for active ingredients and methods for making and using the same
Publication Date: 2013.08.14 MALLARD CREEK POLYMERS INC

AI summary

This invention relates to the field of polymeric materials that can be used in combination with a wide variety of substrates, such as personal care products, textiles, metal, cellulosic materials, plastics, and the like, and to the field of active agents including, for example, antimicrobial, antibacterial and antifungal materials. This invention further relates to latex polymer coatings that comprise at least one active component as well as methods for making and using such latex compositions.