Anionic Membrane Cationic Coating PFAS Removal

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Solution Overview

Problem

Current technologies face challenges in effectively removing poly- and perfluoroalkyl fluorinated materials (PFAS) from aqueous masses, as they are highly persistent and can contaminate environments.

Innovation Solution

A system comprising a first chamber with an aqueous mass containing PFAS, an anode and cathode in electronic connection, and an anionic semipermeable membrane or porous support with a cationic compound adhered to it, positioned between the aqueous mass and the anode to attract and retain PFAS.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional removal technologies are used, then the system structure remains simple, but the removal efficiency of PFAS is insufficient

Engineering Contradiction:
ImprovePFAS removal efficiencyVSAvoidsystem structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs a composite membrane structure consisting of an anionic semipermeable membrane combined with a cationic compound coating. This composite material approach enhances PFAS removal efficiency by creating synergistic effects between the membrane's selective permeability and the cationic compound's electrostatic attraction, while maintaining a relatively simple overall system architecture.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The cationic compound acts as an intermediary substance that facilitates PFAS removal. It is applied to the anionic semipermeable membrane to enhance its PFAS attraction capability through electrostatic interactions, serving as a mediating layer that improves removal efficiency without fundamentally altering the core membrane structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If anionic semipermeable membrane is used, then PFAS retention is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovePFAS retention capabilityVSAvoidmembrane manufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent utilizes an anionic semipermeable membrane with a porous structure that allows selective passage of ions while retaining PFAS. The porous configuration provides surface area for electrostatic interactions with the cationic compound, enhancing retention capability while maintaining manufacturability through established porous material fabrication techniques.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent modifies the membrane's surface properties by applying a cationic compound coating, changing the electrostatic parameters of the membrane surface. This parameter modification enhances PFAS attraction without requiring fundamental changes to the membrane's base structure, simplifying the manufacturing process while improving retention performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient removal of PFAS from the aqueous mass, with the anionic semipermeable membrane retaining the PFAS effectively, thereby reducing contamination levels.

Implementation Method 1

an anionic poly- and/or perfluoroalkyl fluorinated material attractant and/or a semipermeable membrane or porous attracting or binding support for the poly- and/or perfluoroalkyl fluorinated material attractant between the aqueous mass and the anode

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

an anionic semipermeable membrane or porous support with a cationic compound adhered to it, positioned between the aqueous mass and the anode to attract and retain PFAS

Methodology Applied
Scientific EffectSelective permeability: Semipermeable Membrane

Data Source

PatentUS20250083106A1Enhanced system and method for removal of PFAS from aqueous materials
Publication Date: 2025.03.13 BIOLARGO INC
  • US20250083106A1 patent drawing
  • US20250083106A1 patent drawing
  • US20250083106A1 patent drawing

AI summary

A system and method for the removal of poly- and/or perfluoroalkyl fluorinated materials contaminants from an aqueous mass uses a system which includes:a) a first chamber for holding the aqueous mass containing a detectable amount of poly- and/or perfluoroalkyl fluorinated materials;b) an anode and a cathode in electronic connection with the aqueous mass in the first chamber; andc) an anionic semipermeable membrane or porous structure between the aqueous mass and the anode.The anionic semipermeable membrane comprises at least 0.0001% by total weight of the anionic semipermeable membrane of a cationic compound adhered to the anionic semipermeable membrane.