Anionic Membrane with Cationic Coating for PFAS Removal

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Solution Overview

Problem

Current technologies face challenges in effectively removing poly- and perfluoroalkyl fluorinated materials (PFAS) from aqueous masses, as they are highly persistent and can contaminate environments.

Innovation Solution

A system comprising a first chamber with an aqueous mass containing PFAS, an anode and cathode in electronic connection, and an anionic semipermeable membrane or porous support with a cationic compound adhered to it, positioned between the aqueous mass and the anode to attract and retain PFAS.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional removal technologies are used, then the system structure remains simple, but the removal efficiency of PFAS is insufficient

Engineering Contradiction:
Improveremoval efficiencyVSAvoidsystem structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining anionic semipermeable membranes with cationic compounds to create a hybrid removal system. The cationic compound is integrated into or coated on the anionic membrane, creating a composite structure that enhances PFAS removal efficiency through synergistic effects of both components while maintaining a unified system architecture.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The cationic compound acts as an intermediary substance that facilitates PFAS removal by interacting with the anionic PFAS molecules and the anionic membrane. This intermediary mechanism allows for enhanced attraction and retention of PFAS, improving removal efficiency without requiring a completely new system design.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If anionic semipermeable membrane alone is used, then the system is simple, but PFAS retention is insufficient

Engineering Contradiction:
ImprovePFAS retentionVSAvoidmembrane composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The anionic semipermeable membrane is combined with cationic compounds to form a composite membrane structure. This composite approach enhances PFAS retention by creating multiple interaction mechanisms between the membrane material and PFAS molecules, improving reliability while adding controlled complexity to the membrane composition.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The cationic compound is strategically positioned at specific locations on or within the anionic membrane to create localized areas of enhanced PFAS attraction and retention. This local quality enhancement allows the majority of the membrane to maintain its base functionality while specific regions provide amplified PFAS capture capability.

Inventive Principle:
Principle #3Local quality

3Productivity

If cationic compound is adhered to anionic membrane, then PFAS attraction is enhanced, but manufacturing complexity increases

Engineering Contradiction:
ImprovePFAS attractionVSAvoidmembrane preparation
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The cationic compound is pre-applied to the anionic membrane during the manufacturing process or before deployment. This preliminary action of coating or integrating the cationic compound into the membrane structure simplifies the overall system assembly and operation, as the enhanced attraction capability is built-in rather than requiring separate installation steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The cationic compound serves as an intermediary layer between the anionic membrane and PFAS molecules, facilitating enhanced attraction. This intermediary approach allows for improved PFAS capture while the compound acts as a bridge that simplifies the interaction mechanism, making the system easier to manufacture and operate as a unified component.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient removal of PFAS from the aqueous mass, with the anionic semipermeable membrane retaining the PFAS effectively, thereby reducing contamination levels.

Implementation Method 1

an anionic poly- and/or perfluoroalkyl fluorinated material attractant and/or a semipermeable membrane or porous attracting or binding support for the poly- and/or perfluoroalkyl fluorinated material attractant between the aqueous mass and the anode

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

an anionic semipermeable membrane or porous support with a cationic compound adhered to it, positioned between the aqueous mass and the anode to attract and retain PFAS

Methodology Applied
Scientific EffectSemipermeable membrane separation: Semipermeable Membrane

Data Source

PatentUS20250066228A1Enhanced system and method for removal of PFAS from aqueous materials
Publication Date: 2025.02.27 BIOLARGO INC
  • US20250066228A1 patent drawing
  • US20250066228A1 patent drawing
  • US20250066228A1 patent drawing

AI summary

A system and method for the removal of poly- and/or perfluoroalkyl fluorinated materials contaminants from an aqueous mass uses a system which includes:a) a first chamber for holding the aqueous mass containing a detectable amount of poly- and/or perfluoroalkyl fluorinated materials;b) an anode and a cathode in electronic connection with the aqueous mass in the first chamber; andc) an anionic semipermeable membrane or porous structure between the aqueous mass and the anode.The anionic semipermeable membrane comprises at least 0.0001% by total weight of the anionic semipermeable membrane of a cationic compound adhered to the anionic semipermeable membrane.