Anionic Polyester Dispersant for Ink Wettability and Stability

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Solution Overview

Problem

Resin type dispersants in ink dispersion liquids have low initial wettability with coloring materials, leading to increased dispersion time and stress on the material, resulting in insufficient dispersion stability and storage stability of the ink.

Innovation Solution

A dispersant-containing liquid with anionic water-soluble polyester containing carboxylate and/or sulfonate, polyalkylene glycols, and water is used to improve wettability and reduce dispersion time, enhancing the stability and storage stability of the aqueous coloring material dispersion liquid.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If resin type dispersant is used in aqueous dispersion liquid, then affinity for coloring material and low odor are improved, but initial wettability with coloring material is insufficient

Engineering Contradiction:
Improveaffinity for coloring materialVSAvoidinitial wettability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent uses a composite dispersant system combining water-soluble polyester (providing affinity and low odor) with carboxylic acid or sulfonic acid (providing wettability). This composite approach allows the dispersant to simultaneously achieve both high affinity for coloring materials and good initial wettability, resolving the contradiction between these two properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical parameters of the dispersant by introducing carboxylic acid or sulfonic acid groups to the water-soluble polyester structure. This parameter change enhances the surface activity and wettability of the dispersant while maintaining its affinity for coloring materials, thereby resolving the contradiction.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If resin type dispersant is used, then affinity for coloring material is improved, but dispersion time increases

Engineering Contradiction:
Improveaffinity for coloring materialVSAvoiddispersion time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The composite dispersant system combines the high affinity of water-soluble polyester with the rapid wetting capability of carboxylic acid or sulfonic acid. This synergistic combination allows the dispersant to quickly wet the coloring material surface and initiate dispersion, reducing dispersion time while maintaining high affinity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The carboxylic acid or sulfonic acid acts as an intermediary that bridges the water-soluble polyester and the coloring material. It facilitates rapid interaction and wetting between the dispersant and coloring material, thereby reducing dispersion time while preserving the affinity provided by the polyester.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If resin type dispersant is used, then affinity for coloring material is improved, but dispersion stability is insufficient

Engineering Contradiction:
Improveaffinity for coloring materialVSAvoiddispersion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent employs a composite dispersant where water-soluble polyester provides sustained affinity and low odor, while carboxylic acid or sulfonic acid contributes to rapid wetting and dispersion stability. This composite structure ensures both high affinity and adequate dispersion stability simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By modifying the dispersant parameters to include carboxylic acid or sulfonic acid groups, the patent enhances the surface activity and electrostatic interactions that stabilize the dispersion. This parameter change maintains high affinity while improving dispersion stability through enhanced surface coverage and repulsion effects.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If resin type dispersant is used, then affinity for coloring material is improved, but stress on coloring material during dispersion increases

Engineering Contradiction:
Improveaffinity for coloring materialVSAvoidstress on coloring material
Core Design Contradiction:
ReliabilityVSStress or pressure

Solution Approach 1:

The composite dispersant system distributes the interaction with coloring material across two components: water-soluble polyester provides gentle, sustained affinity binding, while carboxylic acid or sulfonic acid provides rapid wetting. This distribution reduces the stress concentration on any single dispersant molecule during the dispersion process.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The carboxylic acid or sulfonic acid serves as an intermediary that rapidly establishes surface coverage and reduces stress on the coloring material by providing immediate wetting action. This intermediary component protects the coloring material from excessive stress during the dispersion process while maintaining affinity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the wettability and dispersion efficiency of organic coloring materials, reducing stress during dispersion and enhancing the dispersion and storage stability of the ink, while maintaining the affinity and adsorptivity of the dispersant, thus improving the overall performance of the ink jet composition.

Implementation Method 1

a dispersant for improving wettability and dispersibility of the coloring material

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

improve wettability and reduce dispersion time

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

an ink in which a coloring material is dispersed in a dispersion medium containing water

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 4

dispersion medium containing water

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 5

the stress on the organic coloring material during dispersion

Methodology Applied
Scientific EffectShear stress: Shear Stress

Data Source

PatentUS20240279499A1Dispersant-Containing Liquid And Aqueous Coloring Material Dispersion Liquid
Publication Date: 2024.08.22 SEIKO EPSON CORP
  • US20240279499A1 patent drawing
  • US20240279499A1 patent drawing
  • US20240279499A1 patent drawing

AI summary

A dispersant-containing liquid of the present disclosure contains anionic water-soluble polyester containing a carboxylate and/or a sulfonate, polyalkylene glycols, and water. When a content of the water-soluble polyester in the dispersant-containing liquid is defined as XPEs [mass %] and a content of the polyalkylene glycols in the dispersant-containing liquid is defined as XPAG [mass %], it is preferable that Expression (4) be satisfied.0.01≤XPAG/XPEs≤2.(4)