Anionic Surfactant Skin Cleanser for Foam and Keratotic Plug Detergency

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Solution Overview

Problem

Existing skin cleansers face challenges in balancing foaming property and detergency against keratotic plugs, and components prone to crystallize and clog foam discharge containers over time.

Innovation Solution

A skin cleanser composition comprising specific anionic surfactants (A1, A2, A3) and keratotic plug-removing agents (B) like 2-amino-2-hydroxymethyl-1,3-propanediol, combined with polyols (C) to enhance detergency and foaming properties while preventing crystallization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If a large amount of anionic surfactant is used in combination with keratotic plugs-removing components, then foaming property is improved, but detergency against keratotic plugs deteriorates

Engineering Contradiction:
Improvefoaming propertyVSAvoiddetergency against keratotic plugs
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the anionic surfactant by specifying particular R1, R2, and R3 groups in the general formula (1). This structural parameter change enables the surfactant to achieve both good foaming properties and effective detergency against keratotic plugs simultaneously, resolving the contradiction between foaming property and detergency effectiveness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite surfactant system by combining specific anionic surfactants with keratolic plugs-removing components (such as 2-amino-2-hydroxymethyl-1,3-propanediol). This composite formulation achieves synergistic effects where the anionic surfactant provides foaming and the amino alcohol provides keratotic plugs removal, while they complement each other's functions.

Inventive Principle:
Principle #40Composite materials

2Reliability

If keratotic plugs-removing components are used in foam discharge container, then detergency against pores is improved, but nozzle clogging occurs due to crystallization over time

Engineering Contradiction:
Improvedetergency against poresVSAvoidcrystallization resistance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces solubilizing agents and co-surfactants as intermediary substances that mediate between the keratotic plugs-removing components and the aqueous environment. These intermediaries prevent crystallization by solubilizing the amino alcohol components, thereby maintaining both detergency effectiveness and compositional stability during long-term storage in foam discharge containers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the physical-chemical parameters of the formulation by controlling pH, adding solubilizing agents, and adjusting the molecular structure of surfactants. These parameter changes reduce the tendency of keratotic plugs-removing components to crystallize, ensuring long-term stability in foam discharge containers while maintaining pore-cleaning effectiveness.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If specific anionic surfactant structure is used, then detergency against keratotic plugs is improved, but foaming property may be compromised

Engineering Contradiction:
Improvedetergency against keratotic plugsVSAvoidfoaming property
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the molecular structure parameters of the anionic surfactant by defining specific R1, R2, and R3 groups in the general formula (1). This precise structural parameter adjustment ensures that the surfactant maintains both strong detergency against keratotic plugs and adequate foaming properties, resolving the contradiction between these two performance aspects.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent detergency against keratotic plugs with stable foaming properties and prevents nozzle clogging in foam discharge containers.

Implementation Method 1

component (A) is one or more anionic surfactant(s) selected from the following components (A1), (A2), and (A3)... excellent foaming property

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

by further comprising polyol(s) with a specific amount in the aforementioned skin cleanser composition, it is possible to not only achieve excellent detergency against pores, excellent foaming property, as well as foam quality, but also inhibit the formation of crystallization of components with keratotic plugs-removing effect

Methodology Applied
Scientific EffectCrystallization inhibition: Solvation

Data Source

PatentEP4623894A1Skin cleanser composition
Publication Date: 2025.10.01 KAO CORP
  • EP4623894A1 patent drawing
  • EP4623894A1 patent drawing
  • EP4623894A1 patent drawing

AI summary

The present invention relates to a skin cleanser composition containing the following components (A)-(B): component (A) is one or more among an N-acyl amino acid represented by formula (1) or a salt thereof (A1), an N-acyl taurine represented by formula (2) or a salt thereof (A2), and a fatty acid having 8-20 carbon atoms or a salt thereof (A3); and component (B) is one or more among TRIS, AMP, AMPD, and MEA. (In the formulae, R1 is a C5-24 linear or branched alkyl or alkenyl group, R2 is hydrogen or a C1-4 alkyl group, R3 and R4 are each hydrogen, a C1-4 alkyl group, a C1-4 hydroxyalkyl group or -(CH 2)m1-COOM2, m1 and n1 are numbers from 0-20, M1 and M2 are each hydrogen, an alkali metal, an alkaline earth metal, a basic amino acid, ammonium, or an alkanolamine; R1 is a C8-20 linear or branched alkyl or alkenyl group, R2 is hydrogen or C1-3 alkyl group, and M is hydrogen, an alkali metal, an alkaline earth metal, an basic amino acid, ammonium, or an alkanolamine.)