Anionic Surfactant Cleaner for Metal Oxide Soil Removal

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Solution Overview

Problem

Metal oxide soils, such as titanium dioxide, accumulate on equipment surfaces in industries like dairy and pharmaceuticals, causing soiling issues that are difficult to remove with conventional cleaning methods, leading to operational inefficiencies and increased costs.

Innovation Solution

A composition comprising an anionic surfactant and a pH adjuster at an acidic pH is applied to surfaces to effectively remove metal oxide soils, utilizing a carrier and rinsing process to achieve cleaning.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cleaning products (e.g., EVAP-O-KLEEN with nitric acid and phosphoric acid) are used to remove metal oxide soils, then cleaning effectiveness is achieved, but device complexity and cost increase due to multiple components and disassembly requirements

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidcleaning system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts and isolates the essential active components from complex conventional cleaning formulations, creating a simplified composition that uses only an anionic surfactant and pH adjuster. This extraction principle reduces device complexity while maintaining cleaning effectiveness by removing unnecessary components from the cleaning system.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical parameters of the cleaning composition by using anionic surfactants with specific HLB values (10-40) and controlling pH levels. These parameter changes enable effective metal oxide removal with a simpler formulation, reducing the need for multiple cleaning agents and complex system configurations.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If manual cleaning methods are used in pharmaceutical industry, then complete soil removal is achieved, but time consumption and labor costs increase significantly

Engineering Contradiction:
Improvesoil removal completenessVSAvoidcleaning time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention enables self-service cleaning through CIP (clean-in-place) technology, where the simplified cleaning composition is applied directly to equipment surfaces and automatically rinsed. This eliminates the need for manual disassembly and cleaning operations, achieving complete soil removal while significantly reducing cleaning time and labor requirements.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention replaces manual mechanical cleaning operations with an automated chemical cleaning system. The anionic surfactant-based composition chemically dissolves metal oxide soils, substituting the need for manual scrubbing and disassembly operations, thereby reducing time loss while maintaining cleaning thoroughness.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Illumination intensity

If titanium dioxide is added to low fat dairy products to whiten them, then product appearance improves, but metal oxide soil buildup on equipment increases

Engineering Contradiction:
Improveproduct brightnessVSAvoidequipment soiling
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The invention converts the harmful effect of titanium dioxide soil buildup into a beneficial cleaning opportunity. The anionic surfactant-based cleaning composition is specifically designed to target and remove metal oxide soils, transforming the soiling problem into a demonstration of the cleaning system's effectiveness. The same titanium dioxide that improves product appearance becomes the test case for the cleaning composition's performance.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Reliability

If heating is applied during pasteurization to kill bacteria, then food safety is improved, but metal oxide soil deposition on equipment increases

Engineering Contradiction:
Improvefood safetyVSAvoidequipment soiling
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention applies preliminary action by using the simplified cleaning composition during or after the pasteurization process to immediately address metal oxide soil deposition. The anionic surfactant-based cleaner is designed to work effectively at the temperatures and conditions present during pasteurization, preventing soil buildup before it becomes problematic rather than requiring separate post-processing cleaning steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves the removal of metal oxide soils from various surfaces, reducing the time and cost associated with cleaning processes while maintaining equipment integrity.

Implementation Method 1

The compositions include an anionic surfactant and a pH adjuster at an acidic pH

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

a pH adjuster at an acidic pH

Methodology Applied
Scientific EffectAcidic protonation:

Data Source

PatentUS7611588B2Methods and compositions for removing metal oxides
Publication Date: 2009.11.03 ECOLAB USA INC
  • US7611588B2 patent drawing
  • US7611588B2 patent drawing

AI summary

The invention relates to methods and compositions for removing metal oxide soils from surfaces. The compositions include an anionic surfactant and a pH adjuster at an acidic pH. In one embodiment, the invention relates to a method of removing a metal oxide soil from a surface by (1) applying a use composition to the surface, the use composition having a pH adjuster in an amount sufficient to provide a use pH at or below 7, an anionic surfactant in an amount to remove a portion of the metal oxide soil, and a carrier, (2) removing the metal oxide soil from the surface with the use composition, and (3) rinsing the surface to remove the use composition and the metal oxide soil.