Optically Anisotropic Compound for Polymer Resin Birefringence Control

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Solution Overview

Problem

Conventional polymer resins for optical use face issues with optical anisotropy, which can lead to signal degradation and viewing angle issues in displays, and existing methods for controlling birefringence either require changing monomer compositions or using inorganic particles that are difficult to disperse, leading to precipitation and reduced transparency.

Innovation Solution

A compound represented by Formula 1 with high optical anisotropy and solubility, which has a meta substituent for increased compatibility with polymer resins, allowing for controlled optical characteristics without phase separation or precipitation, even at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inorganic particles are added to control optical anisotropy, then optical characteristic control is improved, but particle dispersion is poor and aggregation occurs due to low solubility and high density

Engineering Contradiction:
Improveoptical characteristic controlVSAvoidparticle dispersion uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent changes the fundamental parameter of the additive from inorganic particles to organic compounds with specific molecular structures (Formula 1). This parameter change enables the additive to be dissolved in the polymer resin solvent, achieving uniform molecular-level dispersion and eliminating aggregation issues while maintaining optical anisotropy control capability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a specifically designed organic compound (Formula 1) as an intermediary substance that bridges the gap between optical anisotropy control and solvent compatibility. This intermediary compound dissolves in the polymer resin and provides the necessary optical properties without causing phase separation or aggregation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If high anisotropy compounds are used to control optical characteristics, then optical anisotropy is improved, but crystallinity increases and solubility decreases leading to precipitation

Engineering Contradiction:
Improveoptical anisotropyVSAvoidsolubility and compatibility
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of the anisotropic compound by introducing specific meta-substituents (X1-R1 and X2-R2 groups) and adjusting the mesogenic core structure. These parameter changes enable the compound to maintain high optical anisotropy while improving solubility in polymer resins and preventing crystallization-induced precipitation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite molecular structure combining a mesogenic core with specific meta-substituents. This composite structure integrates the optical anisotropy function with enhanced solubility and compatibility characteristics, achieving both optical performance and stability requirements simultaneously.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If monomer composition is changed to control birefringence, then optical characteristic control is improved, but other physical properties of the polymer resin are altered

Engineering Contradiction:
Improvebirefringence controlVSAvoidphysical property consistency
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent introduces a small-molecule compound (Formula 1) as an intermediary additive that provides optical anisotropy control without requiring changes to the polymer resin's monomer composition. This intermediary approach allows independent control of optical properties while maintaining the original polymer resin's physical properties and characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent separates the optical anisotropy control function from the polymer resin base material by using a separate additive compound. This segmentation allows the optical properties to be adjusted independently through the additive concentration rather than changing the fundamental monomer composition, preserving other physical properties.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound effectively controls optical characteristics of polymer resins with high compatibility and stability, preventing phase separation and maintaining transparency, thus improving the optical properties of optical members.

Implementation Method 1

a compound having high compatibility with a polymer resin and high optical anisotropy

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

a compound having high compatibility with a polymer resin and high optical anisotropy

Methodology Applied
Scientific EffectOptical anisotropy: Birefringence

Data Source

PatentUS9422475B2Optically anisotropic compound and resin composition comprising the same
Publication Date: 2016.08.23 LG CHEM LTD
  • US9422475B2 patent drawing
  • US9422475B2 patent drawing
  • US9422475B2 patent drawing

AI summary

Disclosed is a compound having high optical anisotropy and high compatibility with a polymer resin, which is represented by Formula 1 and necessarily has at least one meta substituent. Also, a resin composition including the compound and a polymer resin, and an optical member including the resin composition are disclosed. Since the compound represented by Formula 1 is an anisotropic compound having high compatibility with a polymer resin and high optical anisotropy, in the case of an optical member obtained by using a polymer resin composition including the compound represented by Formula 1, there is no phase separation, and it is possible to achieve a required optical characteristic with only a small amount thereof.