Anisotropic Conductive Back Contact for Thin Film Photovoltaics

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Solution Overview

Problem

Metal electrodes form poor contacts with cadmium telluride in photovoltaic devices, leading to reduced energy conversion efficiency and device deterioration.

Innovation Solution

An anisotropic conductive paste with a polymeric binder and conductive particles is applied to the p-n junction, forming an anisotropic conductive layer that improves adhesion and contact between the cadmium telluride layer and the metal contact layer, facilitating electron flow while isolating individual cells.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If metal electrodes are used as back contact, then device structure is simple, but contact quality with cadmium telluride is poor leading to reduced energy conversion efficiency

Engineering Contradiction:
Improveenergy conversion efficiencyVSAvoidback contact structure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

An anisotropic conductive layer is introduced as an intermediary between the metal back contact electrode and the cadmium telluride absorber layer. This intermediate layer improves electrical contact quality and energy collection efficiency without significantly increasing overall device complexity, resolving the contradiction between simple structure and effective energy conversion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The back contact structure employs a composite material system consisting of metal electrodes combined with an anisotropic conductive layer containing conductive particles embedded in a polymer matrix. This composite approach enhances the electrical interface between the metal and cadmium telluride, improving energy conversion efficiency while maintaining structural feasibility.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If metal electrodes are used as back contact, then manufacturing process is simple, but device lifetime is reduced due to contact deterioration

Engineering Contradiction:
Improvedevice lifetimeVSAvoidback contact fabrication ease
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The anisotropic conductive layer serves as a protective intermediary that prevents direct contact between metal electrodes and cadmium telluride, reducing chemical reactions and contact deterioration. This extends device lifetime while the layer can be applied through conventional printing or coating techniques, maintaining reasonable manufacturing simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The anisotropic conductive layer is applied beforehand as a protective barrier between the metal back contact and the cadmium telluride absorber layer. This pre-established protective interface prevents harmful chemical interactions and contact degradation over time, extending device lifetime without complicating the manufacturing process.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anisotropic conductive layer enhances energy conversion efficiency and device lifetime by providing a reliable conductive back contact that reduces resistance and prevents cell short circuits.

Implementation Method 1

The anisotropic conductive paste includes a polymeric binder and a plurality of conductive particles... providing a reliable conductive back contact that reduces resistance

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

The anisotropic conductive paste includes a polymeric binder... improves adhesion and contact between the cadmium telluride layer and the metal contact layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS8187912B2Methods of forming an anisotropic conductive layer as a back contact in thin film photovoltaic devices
Publication Date: 2012.05.29 FIRST SOLAR INC
  • US8187912B2 patent drawing
  • US8187912B2 patent drawing
  • US8187912B2 patent drawing

AI summary

Thin film photovoltaic devices are generally provided. The device can include a transparent conductive oxide layer on a glass substrate, an n-type thin film layer on the transparent conductive layer, and a p-type thin film layer on the n-type layer. The n-type thin film layer and the p-type thin film layer form a p-n junction. An anisotropic conductive layer is applied on the p-type thin film layer, and includes a polymeric binder and a plurality of conductive particles. A metal contact layer can then be positioned on the anisotropic conductive layer.