Anisotropic Nanoparticle Liquid Crystal Compositions for Tunable Light Control

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Solution Overview

Problem

Current technologies lack the ability to effectively control and tune light and energy flow through materials using surface modified anisotropic nanoparticles in liquid crystals, limiting their application in smart windows and other optical devices.

Innovation Solution

Compositions comprising surface modified anisotropic nanoparticles, such as gold nanorods and nanoplatelets, dispersed in liquid crystals, which can be aligned to control optical properties by adjusting their orientation relative to the liquid crystal director, allowing for tunable light absorption and scattering in response to external stimuli like voltage and light polarization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional materials are used, then material simplicity is maintained, but the ability to control and tune light and energy flow is insufficient

Engineering Contradiction:
Improveability to control and tune light and energy flowVSAvoidmaterial complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent combines anisotropic nanoparticles (such as gold nanorods or nanoplatelets) with liquid crystal materials to create a composite composition. This composite structure enables tunable optical properties including selective light transmission, absorption, and polarization control, directly resolving the contradiction by achieving advanced functionality through material composition rather than simple materials

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The anisotropic nanoparticles are specifically engineered with particular aspect ratios, orientations, and surface modifications to create localized optical anisotropy within the liquid crystal matrix. This allows different regions and orientations of the material to exhibit different optical properties, enabling precise control over light and energy flow while maintaining overall material coherence

Inventive Principle:
Principle #3Local quality

2Adaptability or versatility

If surface modified anisotropic nanoparticles are added to liquid crystals, then tunable optical properties are achieved, but composition complexity increases

Engineering Contradiction:
Improvetunable optical propertiesVSAvoidcomposition complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent systematically varies key parameters including nanoparticle aspect ratio, surface modification chemistry, concentration, and orientation relative to the liquid crystal director to achieve different optical responses. This parameter optimization allows tuning of optical properties such as absorption wavelength, polarization dependence, and transmission characteristics while managing composition complexity through controlled variation

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If nanoparticles are dispersed in liquid crystal, then light transmission control is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvelight transmission controlVSAvoiddispersion preparation complexity
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The anisotropic nanoparticles are pre-synthesized with specific surface modifications that promote uniform dispersion and alignment in liquid crystal matrices. This preliminary surface functionalization prevents aggregation and facilitates subsequent processing, reducing manufacturing complexity while maintaining excellent light transmission control properties

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Surface modification agents act as intermediaries between the nanoparticle core and the liquid crystal matrix, enabling compatible interaction and uniform dispersion. These intermediary layers prevent direct nanoparticle-nanoparticle contact that would cause aggregation, while simultaneously providing anchoring sites for liquid crystal molecules, thereby simplifying the overall manufacturing process

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions enable precise control over light transmission and absorption across various wavelengths, allowing for the selective transmission of visible light while blocking near-infrared radiation, and can be electrically switched to change optical properties, making them suitable for energy-saving applications like smart windows.

Implementation Method 1

The compositions provide tunable methods for modifying light and energy flow

Methodology Applied
Scientific EffectSurface plasmon resonance: Absorption (EM radiation)

Implementation Method 2

can be electrically switched to change optical properties

Methodology Applied
Scientific EffectElectro-optic effect: Electro-Optic Effects

Implementation Method 3

surface modified anisotropic nanoparticles dispersed in a liquid crystal

Methodology Applied
Scientific EffectAnisotropy: Anisotropy

Data Source

PatentUS10640707B2Compositions comprising anisotropic nanoparticle liquid crystal dispersions having tunable optical properties
Publication Date: 2020.05.05 THE REGENTS OF THE UNIVERSITY OF COLORADO
  • US10640707B2 patent drawing
  • US10640707B2 patent drawing
  • US10640707B2 patent drawing

AI summary

Disclosed herein are compositions, comprising one or more types of surface modified anisotropic nanoparticles dispersed in a liquid crystal. The compositions provide tunable methods for modifying light and energy flow.