Anisotropic Thermoelectric Material via Slice Stacking

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Solution Overview

Problem

Existing methods for manufacturing thermoelectric materials are inefficient and economically unviable, as they do not sufficiently improve thermoelectric performance and require long production times, mainly due to limitations in changing composition ratios or using complex methods like molecular beam epitaxy or chemical vapor deposition.

Innovation Solution

A method involving the preparation of slices by mixing powders with a binder, coating, separating, and stacking these slices in a mold, followed by pressing at specific temperatures and pressures to create a functional material with anisotropic properties, such as thermoelectric materials like (BixSb1-x)2Te3, which can include carbon nanotubes and various organic binders.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If molecular beam epitaxy or chemical vapor deposition is used to form stack structure, then thermoelectric performance is improved, but production time is excessively long and manufacturing cost increases

Engineering Contradiction:
Improvethermoelectric performanceVSAvoidproduction time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces complex chemical vapor deposition or molecular beam epitaxy processes with a simpler mechanical pressing process. Slices are prepared by conventional methods and then stacked and pressed mechanically to form the thermoelectric module, eliminating the need for lengthy and expensive vapor deposition processes while achieving comparable or superior thermoelectric performance.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent divides the thermoelectric material into separate slices that are prepared independently and then stacked. This segmentation allows each slice to be manufactured using simple, fast processes, and the final assembly is achieved through mechanical stacking and pressing rather than complex continuous deposition, significantly reducing production time.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If conventional powder sintering and molding is used, then manufacturing process is simple, but thermoelectric performance is insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidthermoelectric performance
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent creates a composite structure by stacking multiple slices of different thermoelectric materials (n-type and p-type) with specific compositions. This composite approach allows optimization of each layer's properties while achieving superior overall thermoelectric performance through the stacked configuration, overcoming the limitations of conventional homogeneous powder sintering.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by preparing slices with specific compositions and properties for different positions in the stack. Each slice can be optimized for its specific function (e.g., different leg lengths, different material compositions), allowing tailored thermoelectric performance in different regions of the module while maintaining simple manufacturing processes.

Inventive Principle:
Principle #3Local quality

3Reliability

If metallic thermoelectric materials are used, then stability and low noise are achieved, but sensitivity is low due to low Seebeck coefficient

Engineering Contradiction:
ImprovestabilityVSAvoidSeebeck coefficient
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent uses composite structures combining different metallic and semiconductor materials in stacked slices. This allows the system to achieve the stability and low noise characteristics of metallic materials while incorporating high Seebeck coefficient materials in specific layers, thereby achieving both reliability and high sensitivity through the composite configuration.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the simple and economical production of multifunctional materials with enhanced thermoelectric performance, including high Seebeck coefficients and dimensionless figure of merit (ZT), demonstrating improved efficiency and applicability in industrial fields.

Implementation Method 1

pressing the slices at a predetermined temperature and pressure

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

pressing the stacked slices at a predetermined temperature and pressure

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

coating the mixed paste on a substrate to form a coated material

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS8894792B2Manufacturing method of functional material using slice stack pressing process and functional material thereby
Publication Date: 2014.11.25 KOREA ELECTROTECH RES INST
  • US8894792B2 patent drawing
  • US8894792B2 patent drawing
  • US8894792B2 patent drawing

AI summary

Disclosed herein are a method for manufacturing a functional material for use in various industrial fields in which anisotropy or physical properties change according to height may be utilized, as well as a functional material manufactured thereby. The method includes the steps of: (1) mixing powders composed of the components of the functional material with a binder to prepare a mixed paste; (2) coating the mixed paste on a substrate, and then separating the coated material from the substrate, thus preparing a slice; (3) repeating step (2) to prepare a plurality of slices, and stacking the slices in a mold; and (4) pressing the stacked slices at a predetermined temperature and pressure. A multifunctional material, such as an anisotropic material having physical properties which change according to the direction of material, or a material having physical properties which change in a graduated manner according to height, may be manufactured in a simple and economical manner.