Annealed Cobalt Plug for Semiconductor Contact

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Solution Overview

Problem

Current semiconductor contact structures face challenges in achieving low electric resistance and uniform lattice structures due to dislocations, voids, and seam-holes in cobalt plugs, which affect the reliability and efficiency of electrical connections.

Innovation Solution

Forming a cobalt plug over a silicide in a semiconductor device and annealing it at a temperature between 200° C to 800° C for a duration of 10 s to 600 s, exposing it to gases like Ar, H2, N2, or NH3 to create a repaired lattice structure with reduced dislocations and voids, thereby forming an annealed cobalt plug with improved conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cobalt plug is formed in semiconductor contact structure, then electrical connection is established, but dislocations and voids in lattice structure increase electric resistance

Engineering Contradiction:
Improveelectrical connection reliabilityVSAvoidlattice structure uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by controlling the deposition conditions of the cobalt plug, including adjusting deposition temperature, pressure, and gas flow rates during physical vapor deposition. These parameter optimizations minimize lattice dislocations and void formation, reducing electric resistance while maintaining reliable electrical connections in the contact structure.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If annealing process is applied to cobalt plug, then lattice structure is repaired and conductivity is improved, but process complexity and manufacturing time increase

Engineering Contradiction:
Improvelattice structure uniformityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs preliminary action by optimizing the initial deposition parameters of the cobalt plug to pre-establish a more uniform lattice structure with fewer dislocations and voids. This preliminary optimization reduces the severity of subsequent annealing required, thereby improving lattice uniformity and conductivity while minimizing the added process complexity and manufacturing time.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If conventional deposition methods are used for cobalt plug, then manufacturing process is simple, but lattice dislocations and seam-holes increase electric resistance

Engineering Contradiction:
Improvedeposition process simplicityVSAvoidelectrical connection reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes deposition parameters including temperature, pressure, and gas composition during physical vapor deposition to achieve a balance between manufacturing simplicity and electrical connection reliability. These controlled parameter changes reduce lattice dislocations and seam-holes, lowering electric resistance while maintaining a relatively simple deposition process suitable for semiconductor manufacturing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The annealed cobalt plug exhibits reduced electric resistance and a more uniform lattice structure, enhancing the reliability and efficiency of electrical connections within the semiconductor device.

Implementation Method 1

annealing it at a temperature between 200° C to 800° C for a duration of 10 s to 600 s

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

annealing the cobalt plug at a first temperature for a first duration while exposing the cobalt plug to a first gas

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS11444028B2Contact structure and formation thereof
Publication Date: 2022.09.13 MAGO BARCA IP LLC
  • US11444028B2 patent drawing
  • US11444028B2 patent drawing
  • US11444028B2 patent drawing

AI summary

A semiconductor device and methods of formation are provided. A semiconductor device includes an annealed cobalt plug over a silicide in a first opening of the semiconductor device, wherein the annealed cobalt plug has a repaired lattice structure. The annealed cobalt plug is formed by annealing a cobalt plug at a first temperature for a first duration, while exposing the cobalt plug to a first gas. The repaired lattice structure of the annealed cobalt plug is more regular or homogenized as compared to a cobalt plug that is not so annealed, such that the annealed cobalt plug has a relatively increased conductivity or reduced resistivity.