Negative Electrode Composite Binder for High-Density Battery Cycling

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Solution Overview

Problem

Secondary batteries face inadequate cyclability and electric resistance characteristics, limiting their performance and efficiency.

Innovation Solution

A negative electrode configuration incorporating an inorganic metal salt and an organic fiber compound is used, which disperses or localizes these materials within the negative electrode active material layer to enhance ion conductivity and reduce electric resistance, thereby protecting the electrode from electrolyte decomposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If secondary battery design is optimized for high energy density, then energy density is improved, but cyclability and electric resistance characteristics become insufficient

Engineering Contradiction:
Improveenergy densityVSAvoidcyclability and electric resistance characteristic
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent employs a composite binder system of cellulose fiber and CMC that enables the negative electrode to achieve high energy density while maintaining excellent cyclability and electric resistance characteristics. The cellulose fiber provides structural framework that accommodates volume changes during cycling, while CMC ensures good adhesion and ion transport. This composite structure allows maximization of active material content (improving energy density) without compromising the electrode's structural integrity or electrical performance over cycles.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different binder materials at different locations and functions within the negative electrode structure. Cellulose fiber primarily provides mechanical support and structural stability, while CMC focuses on surface adhesion to electrode particles and ion conductivity at the electrode-electrolyte interface. This localized functional differentiation allows the electrode to simultaneously achieve high energy density through optimized active material packing and superior cyclability through targeted binder functions at critical locations.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS20230411592A1Negative electrode for secondary battery, and secondary battery
Publication Date: 2023.12.21 MURATA MFG CO LTD
  • US20230411592A1 patent drawing
  • US20230411592A1 patent drawing
  • US20230411592A1 patent drawing

AI summary

A secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The negative electrode includes an inorganic metal salt and an organic fiber compound.