Anode-Free Primary Battery Electrode Assembly Design

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Solution Overview

Problem

Primary batteries face challenges in achieving high energy density while maintaining stability, as they are typically designed without a negative electrode material, limiting their performance in applications requiring low leakage and stable output.

Innovation Solution

The design of an anode-free primary battery electrode assembly that includes a separator, a positive electrode with a current collector and material, and an electrolyte, without a negative electrode material, allowing for increased positive electrode material and electrolyte volume within the same space, utilizing lithium metal oxides and specific organic solvents for enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a conventional primary battery design is used with limited space for positive electrode material, then the battery structure is simple and easy to manufacture, but the energy density is low

Engineering Contradiction:
Improveenergy densityVSAvoidbattery structure
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The invention extracts and removes the negative electrode material from the primary battery, creating an anode-free design. This extraction eliminates the space occupation of negative electrode materials and enables the battery to achieve higher energy density by accommodating more positive electrode material and electrolyte in the same volume, while maintaining a relatively simple overall structure

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the dimensional distribution of battery components by eliminating the negative electrode layer entirely. This dimensional change allows the positive electrode material to occupy the space previously taken by the negative electrode, thereby increasing the volume fraction of active materials and improving energy density without significantly complicating the battery structure

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Quantity of substance

If highly active metals are used in the battery, then the energy density can be increased, but the safety during manufacturing and storage deteriorates

Engineering Contradiction:
Improveenergy densityVSAvoidsafety
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The invention converts the potential harm of highly active metals by removing them from the battery structure entirely. By designing an anode-free battery that uses only stable positive electrode materials and electrolytes without reactive metal anodes, the invention eliminates safety hazards during manufacturing and storage while maintaining high energy density through optimized positive electrode and electrolyte composition

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Duration of action of stationary object

If the battery is designed for single use, then the structure can be simplified, but the storage time and usability are limited

Engineering Contradiction:
Improvestorage timeVSAvoidbattery structure
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The invention enables preliminary charging of the battery before use by designing an anode-free structure with stable positive electrode materials and electrolyte composition. This preliminary action allows the battery to be charged in advance and stored for extended periods without degradation, while maintaining a simple structure that does not require complex protective mechanisms typically associated with rechargeable batteries

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in a primary battery with improved energy density and stability, safer manufacturing and storage due to the absence of highly active metals, and prolonged storage time by enabling activation before use, maintaining performance across multiple cycles.

Implementation Method 1

The electrolyte is provided between the negative electrode current collector and the positive electrode current collector

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

The positive electrode includes a positive electrode current collector and a positive electrode material

Methodology Applied
Scientific EffectElectrochemical reaction: Battery (electricity)

Data Source

PatentUS11626582B2Anode-free primary battery and electrode assembly thereof
Publication Date: 2023.04.11 NAT TAIWAN UNIV OF SCI & TECH
  • US11626582B2 patent drawing
  • US11626582B2 patent drawing
  • US11626582B2 patent drawing

AI summary

The disclosure provides a primary battery and an electrode assembly thereof. The electrode assembly includes a separator, a positive electrode, and a negative electrode current collector. The separator has a positive electrode side and a negative electrode side opposite to each other. The positive electrode is located at the positive electrode side of the separator, and the positive electrode includes a positive electrode current collector and a positive electrode material. The negative electrode current collector is located at the negative electrode side of the separator. The electrode assembly does not include a negative electrode material before charging or activation.