Anode Active Material Polymer Coating Conductive Particles

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Solution Overview

Problem

Secondary batteries face challenges in maintaining stability and power capacity due to side reactions and mechanical damages to anode active material particles during repeated charging and discharging, leading to degraded conductivity and reduced lifespan.

Innovation Solution

An anode active material is developed with a core particle coated with a polymer layer and conductive particles, where the conductive particles have an average diameter greater than the polymer coating thickness, enhancing electron/ion pathways and preventing surface damage, thereby improving stability and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a composition and structure of the anode active material are changed to improve stability of the active material particles, then stability is improved, but conductivity is degraded and power is deteriorated

Engineering Contradiction:
Improvestability of active material particlesVSAvoidpower of secondary battery
Core Design Contradiction:
Stability of the object's compositionVSPower

Solution Approach 1:

The patent applies composite materials by combining the core anode active material particles with a polymer coating layer and conductive particles. The polymer coating provides stability and protection, while the conductive particles (such as carbon black, graphene, or metal nanoparticles) embedded in or on the coating restore and enhance electrical conductivity. This composite structure resolves the contradiction by integrating materials with complementary properties: the polymer matrix ensures structural stability during cycling, while the conductive network maintains efficient electron transport pathways.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a polymer coating is formed on the core particle to prevent side reactions and mechanical damages, then stability is improved, but conductivity is degraded

Engineering Contradiction:
Improvestability of anode active materialVSAvoidconductivity of anode active material
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent uses conductive particles as an intermediary between the polymer coating and the external circuit. These conductive particles are dispersed within the polymer coating layer, creating conductive pathways that bridge the insulating polymer matrix and the active material core. This intermediary approach allows the polymer coating to maintain its protective function while the conductive particles compensate for the insulation effect, ensuring both stability and conductivity are achieved simultaneously.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents side reactions and mechanical damages, maintaining anode activity and power capacity over the battery's lifespan by forming electron/ion channels and buffering resistance increases.

Implementation Method 1

a polymer coating formed on a surface of the core particle

Methodology Applied
Scientific EffectPhysical barrier protection:

Implementation Method 2

conductive particles formed on the polymer coating... forming electron/ion channels

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

at least some of the conductive particles may be inserted into the polymer coating and may protrude to an outside from a surface of the polymer coating... at least some of the conductive particles may penetrate the polymer coating to contact the core particle

Methodology Applied
Scientific EffectPhysical penetration and contact:

Data Source

PatentUS20220285672A1Anode active material for secondary battery, method of preparing the same and secondary battery including the same
Publication Date: 2022.09.08 SK ON CO LTD
  • US20220285672A1 patent drawing
  • US20220285672A1 patent drawing
  • US20220285672A1 patent drawing

AI summary

An anode active material for a secondary battery according to an embodiment of the present invention includes a core particle, a polymer coating formed on a surface of the core particle, and conductive particles formed on the polymer coating. The conductive particles have an average particle diameter greater than a thickness of the polymer coating. The anode active material and a secondary battery having improved stability and reduced resistance are provided using the polymer coating and the conductive particles.