Anodized Aluminum Alloy Surface Appearance and Abrasion Resistance

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Solution Overview

Problem

Consumer electronic products require façades that are both durable and visually appealing, but existing aluminum alloys often fail to meet these criteria effectively in terms of surface appearance and abrasion resistance.

Innovation Solution

The process involves determining a preselected surface appearance and abrasion resistance for an aluminum alloy product, followed by anodizing to create an anodic oxide zone, treating the zone with acid to achieve the desired properties, and optionally coloring and sealing it to maintain the anodic oxide zone's thickness and enhance durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional aluminum alloys are used for consumer electronic façades, then the products can be manufactured with basic structural properties, but the surface appearance and abrasion resistance are insufficient to meet commercial viability criteria

Engineering Contradiction:
Improveabrasion resistanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by performing specific surface preparation steps (mechanical polishing, chemical etching, and brightening) before anodizing to ensure the aluminum alloy surface is properly conditioned. This preliminary preparation enables the subsequent anodizing process to produce consistent, high-quality results with improved abrasion resistance and surface appearance, making the overall manufacturing process more reliable despite the additional steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling various process parameters including anodizing voltage (10-100 V), temperature (0-100°C), electrolyte composition (sulfuric acid, oxalic acid, phosphoric acid), and treatment times. By optimizing these parameters, the process achieves superior abrasion resistance and surface appearance while maintaining manufacturing feasibility through systematic control of process conditions.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the anodic oxide zone is made thicker to improve abrasion resistance, then durability increases, but the surface appearance and color consistency become harder to control

Engineering Contradiction:
ImprovedurabilityVSAvoidsurface appearance consistency
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by treating different surfaces of the aluminum alloy product differently. The exterior viewing surfaces receive optimized anodizing and acid treatment to achieve specific color and gloss characteristics, while other surfaces may receive different treatments based on their functional requirements. This enables simultaneous achievement of durability and appearance consistency on different parts of the same component.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements feedback control by measuring surface properties (color, gloss, thickness) during and after the anodizing and acid treatment processes, then adjusting process parameters to maintain consistency. This feedback mechanism ensures that even with varying oxide zone thicknesses, the final surface appearance meets specified tolerances for color (ΔE≤1.0) and gloss.

Inventive Principle:
Principle #23Feedback

3Manufacturing precision

If acid treatment time is increased to achieve preselected surface appearance, then color and gloss tolerances are met, but the abrasion resistance of the anodic oxide zone decreases

Engineering Contradiction:
Improvecolor toleranceVSAvoidabrasion resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies preliminary action by forming a sufficiently thick anodic oxide zone through extended anodizing before the acid treatment step. This preliminary oxide layer serves as a reservoir that can withstand the acid treatment process while maintaining adequate thickness for abrasion resistance. The preliminary action ensures that even after acid etching to achieve color and gloss specifications, sufficient oxide remains to provide the required durability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses partial or excessive action by applying a longer initial anodizing treatment than the minimum required, creating an oxide zone that is thicker than strictly necessary. This excessive oxide formation allows subsequent acid treatment to achieve the desired surface appearance (color and gloss) while leaving sufficient oxide thickness remaining to maintain abrasion resistance, effectively decoupling the two requirements.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method results in aluminum alloy products with improved surface appearance and abrasion resistance, meeting the commercial viability criteria for consumer products by ensuring the intended viewing surface achieves specific color and gloss tolerances while maintaining high tensile yield strength and abrasion resistance.

Implementation Method 1

the aluminum alloy product is anodized (200) thereby producing an anodic oxide zone in the aluminum alloy product

Methodology Applied
Scientific EffectAnodizing: Anodising

Implementation Method 2

the anodic oxide zone of the aluminum alloy product is treated (300) with an acid for a time sufficient such that the intended viewing surface of the anodized aluminum alloy product achieves one or both of the preselected surface appearance and the preselected abrasion resistance

Methodology Applied
Scientific EffectAcid treatment:

Data Source

PatentUS10087542B2Anodized aluminum alloy products having improved appearance and/or abrasion resistance, and methods of making the same
Publication Date: 2018.10.02 ARCONIC TECHNOLOGIES LLC
  • US10087542B2 patent drawing
  • US10087542B2 patent drawing
  • US10087542B2 patent drawing

AI summary

New methods of producing anodized aluminum alloy products having an improved surface appearance properties are disclosed. The methods may include preparing an aluminum alloy body for anodizing, thereby producing an anodized aluminum alloy body, contacting an intended viewing surface of the anodized aluminum alloy body with an acid, thereby producing a prepared intended viewing surface of the anodized aluminum alloy body, and sealing the prepared intended viewing surface of the anodized aluminum alloy body. The anodized aluminum alloy products may realize a preselected color tolerance, such as realizing a b* value that is within a specified tolerance of a preselected b* value.