Anodized Metal Surface Pre-Dyeing Process

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Solution Overview

Problem

During the anodizing and dyeing process of metal articles, acidic solutions can flow into holes or slits, causing cloudiness in the anodic oxide film and affecting the decorative appearance and durability of the metal surfaces.

Innovation Solution

A surface treatment process that includes pre-dyeing with a complex organic acid and sodium acetate solution to remove residual anodizing solution from holes and slits, followed by dyeing with a controlled pH dye solution and sealing to enhance corrosion and abrasion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If acidic solution is used in surface treatment process, then corrosion resistance and abrasion resistance are improved, but cloudiness occurs in regions of the anodic oxide film due to solution flowing into holes or slits

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidsurface uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing a pre-dyeing treatment before the main dyeing process. The pre-dyeing step fills the holes and slits in the anodic oxide film with a sealing agent, preventing acidic solution from penetrating into these defects during subsequent surface treatment. This preliminary sealing action eliminates the cause of cloudiness while maintaining the protective function of the anodic oxide film.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces an intermediary substance (sealing agent or pre-dye solution) that mediates between the acidic treatment solution and the metal substrate. This intermediary layer fills the holes and slits in the anodic oxide film, acting as a barrier that prevents harmful acidic solution from reaching the metal surface through defects, thereby preventing cloudiness while allowing the acidic solution to maintain its protective function.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If anodizing process is performed to form protective film, then corrosion resistance and abrasion resistance are enhanced, but holes and slits in the film cause solution ingress and surface defects

Engineering Contradiction:
Improveabrasion resistanceVSAvoidsolution ingress
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of holes and slits (which allow solution ingress) into a beneficial feature by using these same openings to deliver sealing agent or dye into the anodic oxide film structure. The pre-dyeing solution or sealing agent penetrates through the holes and slits to fill and seal them, transforming the defect pathways into delivery channels for protective substances that eliminate future solution ingress.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves dyeing quality by preventing solution ingress into metal features, resulting in a metal article with enhanced wear resistance and a bright, uniform appearance.

Implementation Method 1

pre-dyeing with a complex organic acid and sodium acetate solution to remove residual anodizing solution from holes and slits

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

processed to form anodic oxide films via surface treatment process

Methodology Applied
Scientific EffectAnodizing: Anodising

Implementation Method 3

form anodic oxide films via surface treatment process

Methodology Applied
Scientific EffectElectrochemical oxidation: Oxidation

Implementation Method 4

The coloring of the metal articles can be carried out by submersion in a dye solution

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS10662544B2Surface treatment process for metal article
Publication Date: 2020.05.26 HONGFUJIN PRECISION ELECTRONICS ZHENGZHOU
  • US10662544B2 patent drawing

AI summary

A surface treatment process for a metal article provides a uniform and unblemished surface finish to the metal article. The surface treatment process anodizes the metal article to form an anodic oxide layer on a surface, and the metal article is activated using a pre-dyeing solution. The pre-dyeing solution contains complex organic acid and sodium acetate. The anodic oxide layer of the metal article is dyed for color and the dyed anodic oxide layer of the metal article is finally sealed.