Anthocyanin Blue Dye Stabilization via Metal Ion Complexation

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Solution Overview

Problem

Natural blue dyes lack photostability, resulting in fading and a limited color range compared to synthetic dyes, which restricts their application in cosmetics.

Innovation Solution

A blue dye powder is created by stabilizing anthocyanins with specific metal ions such as Al(III), Ca(II), Cu(II), Fe(II), Fe(III), Mg(II), and Zn(II) in combination with tannic acid, enhancing their photostability and bathochromic shift towards blue shades.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If natural blue dyes (anthocyanins) are used, then the cosmetic product is natural and safe, but the photostability is poor and color fades

Engineering Contradiction:
ImprovephotostabilityVSAvoidcolor stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

Tannic acid serves as an intermediary substance that forms a protective complex with anthocyanins and metal ions. This complex prevents direct degradation of anthocyanins by light and oxygen, thereby improving photostability while maintaining the natural status of the cosmetic product.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite dye system comprising anthocyanins, metal ions (such as Al³⁺, Fe³⁺, or Zn²⁺), and tannic acid. This composite structure enhances the photostability of anthocyanins through coordination complexes, while the tannic acid provides additional stabilization, resulting in a natural blue dye with improved color fastness.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If synthetic blue dyes are used, then the color range is wide and photostability is good, but the naturalness and safety are reduced

Engineering Contradiction:
Improvecolor stabilityVSAvoidnaturalness
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The invention modifies the chemical parameters of natural anthocyanins by introducing metal ion complexes and tannic acid interactions. These parameter changes (coordination chemistry, molecular complexation) enhance the stability and color properties of natural dyes, making them comparable to synthetic alternatives while maintaining natural status.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If anthocyanins are stabilized with metal ions and tannic acid, then photostability improves, but the formulation complexity increases

Engineering Contradiction:
ImprovephotostabilityVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges multiple functional components (anthocyanins, metal ions, and tannic acid) into a single integrated stabilization system. This combination achieves enhanced photostability through synergistic interactions, where each component contributes to the overall stability while working together as a unified formulation.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting blue dye powder exhibits improved photostability, maintaining color intensity without fading, thus offering a more attractive and stable blue hue for cosmetic applications.

Implementation Method 1

stabilizing anthocyanins in the presence of certain metal ions

Methodology Applied
Scientific EffectComplexation: Chemical Bonding

Implementation Method 2

stabilizing anthocyanins in the presence of certain metal ions and tannic acid

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Implementation Method 3

enhancing their photostability and bathochromic shift towards blue shades

Methodology Applied
Scientific EffectBathochromic shift: Absorption Spectroscopy

Data Source

PatentUS11554090B2Makeup composition comprising a blue pigment
Publication Date: 2023.01.17 LOREAL SA
  • US11554090B2 patent drawing
  • US11554090B2 patent drawing
  • US11554090B2 patent drawing

AI summary

The invention relates to a cosmetic composition comprising a blue dye powder containing an anthocyan, a metal ion and tannic acid and a cosmetic additive. The invention also relates to a process for making up keratin materials by applying the cosmetic composition to the keratin materials.