Anthracene Derivative Blue Light Emission Efficiency

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Solution Overview

Problem

Current blue light-emitting elements in full-color displays suffer from low emission efficiency and color purity, hindering the development of next-generation flat panel displays.

Innovation Solution

Development of novel anthracene derivatives with specific chemical structures, represented by general formulas, which are used in light-emitting layers to enhance emission efficiency and color purity, particularly for blue light emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in blue light-emitting elements, then the element can be manufactured, but emission efficiency and color purity are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidcolor purity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent modifies the molecular structure parameters of anthracene derivatives by introducing specific substituent groups (Ar1, Ar2, R1-R7) at defined positions on the anthracene core. This structural parameter change optimizes the HOMO-LUMO energy gap and molecular packing, thereby simultaneously improving emission efficiency and achieving high color purity for blue light emission.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures by combining the anthracene core with various aromatic substituent groups (such as phenyl, naphthyl, carbazolyl groups). This composite approach allows tuning of electronic properties and photophysical characteristics, enabling both high emission efficiency and superior color purity that neither component achieves alone.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If blue light-emitting elements are developed for full-color displays, then color completeness is improved, but emission efficiency and color purity remain insufficient

Engineering Contradiction:
Improvecolor completenessVSAvoidemission efficiency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

By systematically varying the substituent groups on the anthracene core (changing molecular parameters), the patent achieves precise control over emission wavelength and efficiency. The specific arrangement of electron-donating and electron-withdrawing groups optimizes charge carrier recombination efficiency while maintaining blue emission, enabling high-performance blue LEDs for complete color displays.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If existing anthracene derivatives are used, then the structure is simple, but emission efficiency and color purity are not sufficient

Engineering Contradiction:
Improvemolecular structure simplicityVSAvoidcolor purity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent introduces functional substituents at specific local positions (2, 7, 9, 10 positions) on the anthracene core rather than uniform modification. This localized functionalization allows precise control over molecular orbitals and packing arrangements, achieving high color purity while maintaining reasonable structural complexity for synthesis.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anthracene derivatives achieve high emission efficiency and color purity, leading to improved performance in blue light-emitting elements, suitable for full-color displays with reduced power consumption and extended lifespan.

Implementation Method 1

Electrons are injected from a cathode into a layer containing an organic compound interposed between a pair of electrodes, and at the same time, holes are injected from an anode into the layer containing an organic compound, whereby a light-emitting element is driven. The electrons injected from the cathode and the holes injected from the anode are recombined with each other in the layer containing an organic compound to form molecular excitons. The molecular excitons release energy in returning to a ground state. When the energy is released as light having a wavelength corresponding to that of visible light, light emission can be seen.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11171292B2Organic compound, anthracene derivative, and light-emitting element, light-emitting device, and electronic device in which the anthracene derivative is used
Publication Date: 2021.11.09 SEMICON ENERGY LAB CO LTD
  • US11171292B2 patent drawing
  • US11171292B2 patent drawing
  • US11171292B2 patent drawing

AI summary

An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (8) are provided. Further, by use of the anthracene derivative represented by the general formula (1), a light-emitting element with high emission efficiency can be obtained. Furthermore, by use of the anthracene derivative represented by the general formula (1), a light-emitting element that emits blue light with high color purity can be obtained.