Anthracene Derivative Blue Light Host Material

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Solution Overview

Problem

Current light-emitting elements that emit blue light are inferior in characteristics compared to those emitting red or green light, primarily due to the need for a light-emitting substance with a large energy gap and host materials with matching energy levels, which affects their performance and efficiency.

Innovation Solution

A novel anthracene derivative with a triarylamine skeleton bonded to the 2-position of 9,10-diarylanthracene is developed, offering a large energy gap suitable for blue light emission and serving as a host in light-emitting layers, enhancing the performance of blue light-emitting elements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a light-emitting substance with a large energy gap is used to emit blue light, then blue light emission is achieved, but the characteristics (lifetime, power consumption, efficiency) are inferior compared to red or green light-emitting elements

Engineering Contradiction:
Improveblue light emissionVSAvoidelement characteristics
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The invention changes the molecular structure parameters of the light-emitting substance by introducing specific substituents (triarylamine group at 2-position, phenyl group at 9,10-positions) of the anthracene core, thereby optimizing the energy gap and HOMO/LUMO levels to achieve both blue light emission and improved element characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite molecular structure combining anthracene core with triarylamine and phenyl groups, where each component contributes specific properties: anthracene provides the rigid core and blue emission, triarylamine provides hole transport capability and stabilizes the structure, and phenyl groups extend conjugation to optimize energy levels

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If host materials with matching energy levels are used to support the light-emitting substance, then blue light emission is achieved, but the performance and efficiency are limited

Engineering Contradiction:
Improveblue light emissionVSAvoidelement efficiency
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

The invention optimizes the energy level parameters (HOMO and LUMO) of the light-emitting substance by modifying the anthracene structure, ensuring proper energy level alignment with common host materials to facilitate efficient charge injection and transport, thereby improving element efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anthracene derivative enables the production of light-emitting elements with high color purity and improved characteristics for blue light emission, addressing the limitations of existing blue light-emitting materials by providing a suitable energy gap and stability, thus improving the overall performance and efficiency of blue light-emitting devices.

Implementation Method 1

In an organic EL element, when voltage is applied between a pair of electrodes which interpose a light-emitting layer containing a light-emitting organic compound, electrons and holes are injected from the electrodes and are recombined to form an excited state, and when the excited state returns to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

A wavelength of light emitted from a light-emitting substance is peculiar to the light-emitting substance; thus, by using different types of organic compounds as light-emitting substances, light-emitting elements which exhibit various wavelengths, i.e., various colors can be obtained.

Methodology Applied
Scientific EffectEnergy absorption and emission: Absorption (EM radiation)

Data Source

PatentUS8741449B2Anthracene derivative, light-emitting material, material for light-emitting element, composition for coating, light-emitting element, light-emitting device, and electronic device
Publication Date: 2014.06.03 SEMICON ENERGY LAB CO LTD
  • US8741449B2 patent drawing
  • US8741449B2 patent drawing
  • US8741449B2 patent drawing

AI summary

An anthracene derivative represented by the general formula (G1) is provided. The anthracene derivative represented by the general formula (G1) is a novel anthracene derivative having a wide band gap. Further, the anthracene derivative has a large energy gap and can be very suitably used as a material for a light-emitting element which exhibits blue light emission.