Anthracene Derivative Host Material for OLED Efficiency and Stability

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Solution Overview

Problem

Current organic electronic devices, such as OLEDs, face inefficiencies, high drive voltage, and reduced stability due to the limitations of existing materials used in their organic material layers, particularly in light emitting and charge transporting layers.

Innovation Solution

A novel anthracene derivative is synthesized and used as a hole injecting, hole transporting, electron injecting, electron transporting, or light emitting material, functioning as a host or dopant in organic electronic devices, enhancing efficiency, reducing drive voltage, and improving stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in OLEDs, then the device structure is simple, but the efficiency is low and drive voltage is high

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoiddrive voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the chemical structure of anthracene by introducing specific substituents (compounds 1-25 with various aryl, heteroaryl, and amino groups) to optimize HOMO/LUMO energy levels, hole mobility, and electron mobility. These parameter changes in molecular structure directly improve light emitting efficiency while reducing the drive voltage required for device operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite organic material systems by combining anthracene derivatives with other organic compounds to form host-guest systems, charge transport layers, and light emitting layers. These composite material structures synergistically improve efficiency and reduce drive voltage through enhanced charge transport and energy transfer mechanisms

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing organic materials are used, then manufacturing is straightforward, but stability and lifespan are reduced

Engineering Contradiction:
Improvedevice stabilityVSAvoiddevice lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent optimizes molecular parameters of anthracene derivatives including steric hindrance, molecular weight, and functional group composition to enhance thermal stability, morphological stability, and resistance to degradation. These parameter optimizations directly improve device stability and extend operational lifespan while maintaining compatibility with standard manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The molecular结构设计 incorporates stabilizing features such as rigid aromatic cores, protective substituent groups, and balanced charge transport capabilities that preemptively resist degradation mechanisms before they occur during device operation, thereby extending lifespan and maintaining stability

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Productivity

If single materials are used for light emitting, then device structure is simple, but color purity and efficiency deteriorate

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoidcolor purity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent employs host-guest composite systems where anthracene derivatives serve as hosts for dopant molecules, enabling efficient energy transfer and precise color control. This composite approach achieves high color purity through selective dopant emission while maintaining high efficiency through effective energy transfer from the host matrix

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention uses different anthracene derivative compounds for different functional layers (hole transport, electron transport, light emitting) and different color regions (blue, green, red emitters), optimizing local material properties to achieve high color purity in each region while maintaining overall device efficiency

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anthracene derivative significantly improves the efficiency, drive voltage, and stability of organic electronic devices, particularly in OLEDs, by serving as a green host or dopant, enabling better performance and longer lifespan.

Implementation Method 1

a hole injecting or hole transporting material, an electron injecting or electron transporting material, or a light emitting material for driving the device

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

a hole injecting or hole transporting material, an electron injecting or electron transporting material, or a light emitting material for driving the device

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 3

when the excitons drop to a ground state, lights are emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 4

excitons which are generated in the light emitting layer are transported to the dopant, thus emitting a light having a high efficiency

Methodology Applied
Scientific EffectEnergy transfer:

Data Source

PatentEP1902013B1Novel anthracene derivatives, process for preparation thereof, and organic electronic light emitting device using the same
Publication Date: 2016.06.01 LG CHEM LTD
  • EP1902013B1 patent drawingFigure 1
  • EP1902013B1 patent drawing
  • EP1902013B1 patent drawing

AI summary

The present invention relates to a novel anthracene derivative, a process for preparation thereof, and an organic electronic device using the same. The anthracene derivative according to the present invention can serve as a hole injecting material, a hole transporting material, an electron injecting material, an electron transporting material, or a light emitting material, and particularly as a light emitting host or dopant, especially as a green host or dopant singly, in an organic electronic device including an organic light emitting device. The organic electronic device according to the present invention exhibits excellent characteristics in efficiency, drive voltage, life time, and stability.