Anthracene Derivatives for OLED Efficiency and Stability

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Solution Overview

Problem

Current organic light emitting devices lack stable and efficient materials for their organic material layers, which limits their efficiency, driving voltage, and lifespan.

Innovation Solution

Development of novel anthracene derivatives that can be used in the organic material layers of organic electronic devices, specifically in the electron transport and light emitting layers, to enhance device efficiency, reduce driving voltage, and increase stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in organic light emitting devices, then the device can operate with basic functionality, but the efficiency and stability are insufficient

Engineering Contradiction:
Improvedevice stabilityVSAvoiddevice efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the chemical structure of anthracene derivatives by introducing specific substituents (such as carbazole groups, arylamino groups, and heterocyclic groups) at defined positions (2, 6, 7, or 9 positions). These structural parameter changes optimize the HOMO/LUMO energy levels, electron mobility, and thermal stability of the material, simultaneously improving both device efficiency and stability without compromise

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite organic material systems by combining anthracene core structures with various functional groups (electron-transporting groups, hole-transporting groups, light-emitting groups) to form hybrid molecules that exhibit synergistic properties. These composite molecular structures achieve both high efficiency charge transport and long-term operational stability

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If the organic material layer uses existing materials, then the device structure is simple, but the driving voltage remains high and lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoiddriving voltage
Core Design Contradiction:
Duration of action of stationary objectVSUse of energy by stationary object

Solution Approach 1:

The patent optimizes the energy level parameters (HOMO and LUMO levels) of anthracene derivatives to achieve better alignment with electrode work functions and adjacent organic layers. This parameter optimization reduces energy barriers for charge injection and transport, lowering driving voltage while extending device lifespan through reduced energy loss and heat generation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops organic small molecule materials that can be deposited in thin films (50-200 nm thickness) to achieve long device lifespan without requiring thick, energy-intensive material layers. The high efficiency of these molecular materials allows ultra-thin active layers that consume less energy while maintaining long operational stability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these anthracene derivatives in organic electronic devices results in improved efficiency, reduced driving voltage, extended lifespan, and increased stability, as demonstrated by the organic light emitting devices' performance metrics.

Implementation Method 1

an organic light emitting phenomenon means a phenomenon that converts electric energy into light energy by using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

holes are injected from an anode to the organic layer and electrons are injected from a cathode to the organic layer, and when the injected holes and the electrons meet each other, an exciton is formed

Methodology Applied
Scientific EffectCharge injection and transport: Conduction (electrical)

Implementation Method 3

by mixing a dopant that has a energy bandwidth gap that is lower than that of host constituting mainly the light emitting layer and has excellent light emission efficiency with a light emitting layer in a small amount, the exciton that is generated in the host is transported to the dopant to ensure light having high efficiency

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Data Source

PatentEP2327679B1Novel anthracene derivatives and organic electronic device using same
Publication Date: 2017.03.01 LG CHEM LTD
  • EP2327679B1 patent drawing
  • EP2327679B1 patent drawing
  • EP2327679B1 patent drawing

AI summary

The present invention provides a novel anthracene derivatives and an organic electronic device using the same. Thte organic electronic device according to the present invention shows excellent properties in terms of efficiency, a driving voltage, and a life span.