Anti-freezing Sulfonated Dispersant with Ethylene Glycol

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Solution Overview

Problem

Sulfonated dispersants used in industrial applications typically freeze at around 0°C, posing challenges during transportation, storage, and application.

Innovation Solution

A composition comprising a sulfonated dispersant and a solvent, such as ethylene glycol, is developed to lower the freezing point of the dispersant, allowing its use at low temperatures, with specific weight percentages of the sulfonated dispersant and solvent optimized to prevent freezing and sedimentation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If dispersants are used in aqueous solution form, then they maintain good dispersing performance, but they freeze at around 0°C which impacts transportation, storage, and application

Engineering Contradiction:
Improvedispersing performanceVSAvoidfreezing point
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the physical-chemical parameters of the dispersant by adding co-solvents (alcohols, glycols, carboxylic acids) to the aqueous solution, thereby lowering the freezing point from 0°C to below -20°C while maintaining the dispersing performance. This parameter modification allows the dispersant to remain liquid and functional in low-temperature environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid formulation by combining the aqueous dispersant solution with multiple co-solvent components. This composite system integrates the dispersing properties of the sulfonated dispersant with the low-temperature fluidity of the co-solvents, achieving both dispersing performance and anti-freezing capability simultaneously.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the freezing point of dispersant is lowered by adding co-solvents, then the dispersant can be used at low temperatures, but the composition complexity increases

Engineering Contradiction:
Improvelow temperature usabilityVSAvoidcomposition complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent selects co-solvents that serve multiple functions: they lower the freezing point, maintain liquidity at low temperatures, and preserve the dispersing effectiveness. By choosing substances like alcohols, glycols, and carboxylic acids that perform multiple roles, the patent reduces the need for additional components, thereby limiting the increase in composition complexity while achieving low-temperature adaptability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The anti-freezing dispersant composition effectively prevents freezing and sedimentation at temperatures as low as −25°C, enabling its use in industrial processes without freezing, thereby enhancing process efficiency and operational flexibility.

Implementation Method 1

A composition comprising a sulfonated dispersant and a solvent, such as ethylene glycol, is developed to lower the freezing point of the dispersant

Methodology Applied
Scientific EffectFreezing point depression:

Implementation Method 2

Dispersant antifoulants that function as colloidal stabilizers that keep the foulants suspended and prevent them from depositing on equipment surfaces

Methodology Applied
Scientific EffectColloidal stabilization: Colloid

Data Source

PatentUS12065606B2Anti-freezing dispersant and manufacturing process thereof
Publication Date: 2024.08.20 ECOLAB USA INC
  • US12065606B2 patent drawing

AI summary

The present disclosure provides methods of treating industrial processes with compositions, methods of manufacturing the compositions, and various anti-freezing compositions suitable for use in the industrial processes. The anti-freezing dispersant compositions may include, for example, sulfonated dispersants and winterization solvents. The anti-freezing dispersant compositions may prevent fouling in the industrial processes.