Anti-Reflection Coating Design for Lens Tarnish and Reflection

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Solution Overview

Problem

Existing anti-reflection coatings for single-lens reflex camera lenses suffer from high reflection loss, leading to flare and ghost effects in photographs, and fail to adequately prevent tarnish, particularly in wide-angle lenses with large incident angles.

Innovation Solution

An anti-reflection coating comprising 7 layers, with an alumina-based innermost layer and a porous silica-based outermost layer, featuring specific refractive indices and optical thicknesses, and utilizing materials like Ta2O5, ZrO2, and MgF2, formed using physical vapor deposition and sol-gel methods, to achieve low reflectance and tarnish resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a multi-layer dielectric coating is formed to reduce reflection loss, then anti-reflection performance is improved, but the coating complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvereflection lossVSAvoidcoating structure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The coating is divided into multiple dielectric layers with alternating high and low refractive indices (e.g., MgF2, SiO2, Ta2O5, ZrO2 layers). Each layer is optimized for specific thickness and refractive index to create constructive interference for desired wavelengths and destructive interference for unwanted reflections, thereby reducing overall reflection loss while managing complexity through systematic layering

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes specific parameters including the refractive indices of individual layers (e.g., n1=1.38 for MgF2, n2=1.46 for SiO2), the thickness of each layer (e.g., d1=50-150 nm, d2=50-150 nm), and the number of layers to achieve optimal anti-reflection performance across the visible spectrum while controlling manufacturing complexity

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional anti-reflection coatings are applied to prevent tarnish, then tarnish resistance is improved, but reflection loss increases

Engineering Contradiction:
Improvetarnish resistanceVSAvoidreflection loss
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent employs a composite coating structure combining multiple dielectric materials with different optical properties (MgF2, SiO2, Ta2O5, ZrO2) in specific layering sequences. This composite structure achieves both tarnish resistance through the protective outer layers and low reflection loss through the optimized optical interference effects of the multi-layer system

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different regions of the coating have different functions: inner layers are optimized for optical interference to reduce reflection, while outer layers provide tarnish protection. The patent assigns specific materials and thicknesses to different positions in the coating stack to achieve both objectives simultaneously without compromise

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If the number of coating layers is reduced to simplify manufacturing, then ease of manufacture is improved, but anti-reflection performance deteriorates

Engineering Contradiction:
Improvecoating application simplicityVSAvoidreflection loss
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent achieves effective anti-reflection performance with a moderate number of layers (typically 5-10 layers) rather than requiring excessive layering. Each layer is carefully designed with optimal thickness and material selection to maximize the anti-reflection effect per layer, reducing the total number of layers needed while maintaining high performance

Inventive Principle:
Principle #16Partial or excessive action

4Ease of manufacture

If coatings with high refractive index materials are used to reduce the number of layers, then ease of manufacture is improved, but reflectance at visible wavelengths increases

Engineering Contradiction:
Improvecoating application simplicityVSAvoidreflectance
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent carefully selects and optimizes the refractive indices of individual layers (e.g., using MgF2 with n=1.38, SiO2 with n=1.46, Ta2O5 with n=2.0, ZrO2 with n=2.1) to create a gradient effect that reduces reflectance. The specific combination and ordering of these materials with different refractive indices achieves low reflectance across the visible spectrum while keeping the number of layers manageable

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating provides excellent anti-reflection performance with reduced flare and ghost effects, while preventing tarnish, even with fewer layers, enhancing image quality in single-lens reflex cameras.

Implementation Method 1

Each lens has a laminated anti-reflection coating comprising pluralities of dielectric layers each having a different refractive index from that of a lens substrate and a thickness of 1⁄2λ or 1⁄4λ, wherein λ is a center wavelength, to utilize interference effects

Methodology Applied
Scientific EffectInterference: Interference

Implementation Method 2

formed using physical vapor deposition and sol-gel methods

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 3

formed using physical vapor deposition and sol-gel methods

Methodology Applied
Scientific EffectSol-gel: Sol

Data Source

PatentUS8199404B2Anti-reflection coating, optical member, exchange lens unit and imaging device
Publication Date: 2012.06.12 RICOH IMAGING COMPANY
  • US8199404B2 patent drawing
  • US8199404B2 patent drawing
  • US8199404B2 patent drawing

AI summary

An anti-reflection coating comprising first to seventh layers formed on a substrate in this order, the first layer being an alumina-based layer, the seventh layer being a porous, silica-based layer, and each of the first to seventh layers having predetermined refractive index and optical thickness in a wavelength range of 400-700 nm.