Anti-Reflection Optical Member with Flat Metal Particles

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Solution Overview

Problem

Existing anti-reflection optical members suffer from reduced transmittance due to light absorption and have a narrow bandwidth for effective anti-reflection, particularly in configurations using metal microparticles or chain-like metal colloids.

Innovation Solution

A laminated structure comprising a transparent substrate, a metal-microparticle-containing layer with flat metal particles, and a dielectric layer, where at least 60% of metal microparticles are flat with a high aspect ratio, oriented to minimize conductive paths and maximize transmittance, and the dielectric layer thickness is optimized to interfere and cancel reflected light, enhancing anti-reflection across a wider bandwidth.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a layer containing metal microparticles is used to increase anti-reflection effect at wavelength of 550 nm, then the anti-reflection effect is improved, but the transmittance of incident light is lowered due to absorption

Engineering Contradiction:
Improveanti-reflection effectVSAvoidtransmittance
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The invention changes the geometric parameters of metal microparticles from spherical to flat shapes with high aspect ratios (diameter/thickness ≥ 3). This parameter change reduces the absorption cross-section of the particles while maintaining their anti-reflection functionality through controlled orientation and distribution in the coating layer.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating layer combining flat metal particles (silver, aluminum, or copper) with a binder resin. This composite structure allows the metal particles to provide anti-reflection effects while the binder matrix reduces overall light absorption and enables controlled particle orientation to minimize conductive path formation.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If a layer containing metal microparticles is used to increase anti-reflection effect at wavelength of 550 nm, then the anti-reflection effect is improved, but the bandwidth in which a large anti-reflection effect can be obtained is very narrow

Engineering Contradiction:
Improveanti-reflection effectVSAvoidbandwidth
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The invention uses flat metal particles with high aspect ratios (diameter/thickness ≥ 3) oriented at specific angles (0° to 30° to the surface). This geometric parameter change creates a broader resonance response across the visible spectrum compared to spherical particles, expanding the effective bandwidth from a narrow peak at 550 nm to a wide range covering visible light.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention transitions from zero-dimensional spherical particles to two-dimensional flat particles with specific orientation angles. This dimensional change introduces angular control over optical response, enabling broader spectral coverage by exploiting the anisotropic optical properties of oriented flat particles.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Reliability

If chain-like metal colloid is used to have an antistatic function, then the antistatic property is improved, but the transmittance is lowered due to absorption of incident light

Engineering Contradiction:
Improveantistatic propertyVSAvoidtransmittance
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The invention creates a composite structure where metal particles are dispersed in a binder resin rather than forming continuous chains. This composite approach maintains antistatic functionality through distributed charge dissipation while the resin matrix prevents direct particle contact, reducing absorption and improving transmittance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention extracts the harmful conductive path formation from the system by preventing direct particle-to-particle contact. Instead of using chain-like structures that provide continuous conduction paths (and thus high absorption), the invention uses isolated or sparsely connected particles that maintain antistatic function through alternative mechanisms while minimizing light absorption.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high transmittance (>80%) and a wide bandwidth (>100 nm) with low reflectance (<0.5%) across visible light wavelengths, effectively addressing the limitations of absorption and narrow bandwidth in previous technologies.

Implementation Method 1

a thickness of the dielectric layer is a thickness at which light reflected on a surface of the dielectric layer in a case where the incident light enters the laminated structure from the surface of the dielectric layer interferes with and is canceled out by light reflected on an interface between the dielectric layer and the metal-microparticle-containing layer

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 2

main flat surfaces of the flat metal particles are oriented in a plane at in a range of 0° to 30° to a surface of the metal-microparticle-containing layer

Methodology Applied
Scientific EffectParticle orientation:

Data Source

PatentUS10310143B2Anti-reflection optical member
Publication Date: 2019.06.04 FUJIFILM CORP
  • US10310143B2 patent drawing
  • US10310143B2 patent drawing
  • US10310143B2 patent drawing

AI summary

An anti-reflection optical member has a laminated structure including: a transparent substrate having a first refractive index greater than that of a predetermined medium; a metal-microparticle-containing layer containing metal microparticles; and a dielectric layer having a second refractive index greater than that of the predetermined medium, in this order. At least 60% of the metal microparticles are flat particles with a diameter-to-thickness ratio of 3 or more. Principal planes of the flat metal particles are surface-oriented in the range from 0° to 30° relative to the surface of the metal-microparticle-containing layer. In the metal-microparticle-containing layer, the metal microparticles are disposed without forming a conductive path. The dielectric layer has such a thickness that light reflected at the surface of the dielectric layer of incident light entering the laminated structure from the surface is interfered and canceled by light reflected at the interface between the dielectric layer and the metal-microparticle-containing layer.