Anti-Reflective Coatings for Photovoltaic Modules

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Solution Overview

Problem

Existing anti-reflective coatings for photovoltaic modules are inefficient due to the requirement for multiple layers of varying composition and refractive index, which complicates their application and performance.

Innovation Solution

A composition comprising polymeric particles with specific size, hardness, and refractive index characteristics, combined with a film-forming polymer, is used to create an anti-reflective film with controlled refractive index differences and particle spacing, optimized for use in photovoltaic modules.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multiple layers of varying composition and refractive index are used, then anti-reflective performance is improved, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improveanti-reflective performanceVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple layers of varying composition and refractive index into a single-layer coating system. The composition includes polymer particles (30-70 wt%) with refractive index 1.45-1.65 and a binder polymer with refractive index 1.30-1.55, creating effective refractive index gradients within one layer that previously required multiple separate layers, thereby simplifying the coating structure while maintaining anti-reflective performance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a composite material system consisting of dispersed polymer particles within a binder polymer matrix. This composite structure allows tuning of the effective refractive index by adjusting particle size distribution, particle concentration, and particle-binder interfacial properties, enabling single-layer anti-reflective coatings to achieve the optical performance previously requiring multiple layers

Inventive Principle:
Principle #40Composite materials

2Reliability

If multiple layers of varying composition and refractive index are used, then anti-reflective performance is improved, but ease of manufacture deteriorates

Engineering Contradiction:
Improveanti-reflective performanceVSAvoidcoating manufacturing ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges multiple manufacturing steps and material applications into a single coating process. The composition is applied as a single layer that forms a unified film, eliminating the need for sequential application, drying, and curing of multiple separate layers, thereby significantly improving ease of manufacture while achieving comparable anti-reflective performance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent changes the physical and chemical parameters of the coating system by using a dispersion of polymer particles in a binder polymer with specific glass transition temperature ranges. This allows the coating to be applied from a stable dispersion that forms a homogeneous film upon drying, simplifying the manufacturing process compared to applying multiple layers with different compositions

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides an effective anti-reflective coating that enhances the performance of photovoltaic modules by minimizing reflectance and optimizing light transmission, thereby improving energy efficiency.

Implementation Method 1

an average refractive index difference measured from 400 nm to 1100 nm between the polymeric particles and the film-forming polymer is no greater than 0.04, and an average refractive index difference measured above 1100 nm or below 400 nm between the polymeric particles and the film-forming polymer is at least 0.04

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS8563130B2Anti-reflective coatings
Publication Date: 2013.10.22 ROHM & HAAS CO

AI summary

A composition comprising polymeric particles having an average particle diameter from 0.5 to 30 μm and Vicker's scale hardness from 100 to 700 Kgf/mm2. The composition also contains a film-forming polymer having Tg no greater than 80° C. The average refractive index difference measured from 400 nm to 1100 nm between the polymeric particles and the film-forming polymer is no greater than 0.04.